Stochastic fluctuations and chiral symmetry breaking: Exact solution of Lente model
文献类型：期刊论文
| 作者 | Shao, Jiushu; Liu, Lan |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY A
 |
| 出版日期 | 2007-09-27 |
| 卷号 | 111期号:38页码:9570-9572 |
| ISSN号 | 1089-5639 |
| DOI | 10.1021/jp0739364 |
| 英文摘要 | The stochastic description for the autocatalytic process has been proposed by Lente (J. Phys. Chem. A 2004, 108, 9475) to demonstrate chiral symmetry breaking. He assumed that the number of reacting molecules is macroscopic and that no products are present initially. The Lente model consisting of a finite number of molecules that may include the product molecules as chiral seeds is explored and the characteristics of stochastic 14 distributions of the product are examined. It is shown that the presence of racemic product in the substrate reduces the possibility of chiral syrnmetry breaking while a few more molecules of a specific enantiomer added can yield chiral dominance for strong autocatalysis. Besides., small reactive volumes or dense reactant concentrations have a preference for chiral symmetric breaking. |
| 语种 | 英语 |
| WOS记录号 | WOS:000249655600051 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/61773]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Shao, Jiushu |
| 作者单位 | 1.Beijing Normal Univ, Coll Chem, Beijing 100875, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shao, Jiushu,Liu, Lan. Stochastic fluctuations and chiral symmetry breaking: Exact solution of Lente model[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2007,111(38):9570-9572. |
| APA | Shao, Jiushu,&Liu, Lan.(2007).Stochastic fluctuations and chiral symmetry breaking: Exact solution of Lente model.JOURNAL OF PHYSICAL CHEMISTRY A,111(38),9570-9572. |
| MLA | Shao, Jiushu,et al."Stochastic fluctuations and chiral symmetry breaking: Exact solution of Lente model".JOURNAL OF PHYSICAL CHEMISTRY A 111.38(2007):9570-9572. |
入库方式： OAI收割
来源：化学研究所
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