中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis and structure of a 1,6-hexyldiamine heptaborate, [H3N(CH2)(6)NH3][B7O10(OH)(3)]

文献类型:期刊论文

作者Yang, Sihai; Li, Guobao; Tian, Shujian; Lia, Fuhui; Xiong, Ming; Lin, Jianhua
刊名JOURNAL OF SOLID STATE CHEMISTRY
出版日期2007-08-01
卷号180期号:8页码:2225-2232
关键词Polyborate Heptaborate Solvothermal Reaction Structure Space Group P2(1)/n Supramolecular
ISSN号0022-4596
DOI10.1016/j.jssc.2007.05.029
英文摘要A new 1,6-hexyldiamine heptaborate, [H3N(CH2)(6)NH3][B7O10(OH)(3)] (1), has been solvothermally synthesized and characterized by single-crystal X-ray diffraction, FTIR, elemental analysis, and thermogravimetric analysis. Compound I crystallizes in monoclinic system, space group P2(1)/n with a = 8.042(2) angstrom, b = 20.004(4) angstrom, c = 10.103(2) angstrom, and beta = 90.42(3)degrees. The anionic [B7O10(OH)(3)]n(2n-) layers are interlinked via hydrogen bonding to form a 3D supramolecular network containing large channels, in which the templated [H3N(CH2)(6)NH3](2+) cations are located. (C) 2007 Elsevier Inc. All rights reserved.
语种英语
WOS记录号WOS:000249186100006
出版者ACADEMIC PRESS INC ELSEVIER SCIENCE
源URL[http://ir.iccas.ac.cn/handle/121111/61797]  
专题中国科学院化学研究所
通讯作者Li, Guobao
作者单位1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, BNLMS, Beijing 100871, Peoples R China
2.China Univ Geosci, Xray Lab, Beijing 100083, Peoples R China
推荐引用方式
GB/T 7714
Yang, Sihai,Li, Guobao,Tian, Shujian,et al. Synthesis and structure of a 1,6-hexyldiamine heptaborate, [H3N(CH2)(6)NH3][B7O10(OH)(3)][J]. JOURNAL OF SOLID STATE CHEMISTRY,2007,180(8):2225-2232.
APA Yang, Sihai,Li, Guobao,Tian, Shujian,Lia, Fuhui,Xiong, Ming,&Lin, Jianhua.(2007).Synthesis and structure of a 1,6-hexyldiamine heptaborate, [H3N(CH2)(6)NH3][B7O10(OH)(3)].JOURNAL OF SOLID STATE CHEMISTRY,180(8),2225-2232.
MLA Yang, Sihai,et al."Synthesis and structure of a 1,6-hexyldiamine heptaborate, [H3N(CH2)(6)NH3][B7O10(OH)(3)]".JOURNAL OF SOLID STATE CHEMISTRY 180.8(2007):2225-2232.

入库方式: OAI收割

来源:化学研究所

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