Synthesis and structure of a 1,6-hexyldiamine heptaborate, [H3N(CH2)(6)NH3][B7O10(OH)(3)]
文献类型:期刊论文
作者 | Yang, Sihai; Li, Guobao; Tian, Shujian; Lia, Fuhui; Xiong, Ming; Lin, Jianhua |
刊名 | JOURNAL OF SOLID STATE CHEMISTRY
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出版日期 | 2007-08-01 |
卷号 | 180期号:8页码:2225-2232 |
关键词 | Polyborate Heptaborate Solvothermal Reaction Structure Space Group P2(1)/n Supramolecular |
ISSN号 | 0022-4596 |
DOI | 10.1016/j.jssc.2007.05.029 |
英文摘要 | A new 1,6-hexyldiamine heptaborate, [H3N(CH2)(6)NH3][B7O10(OH)(3)] (1), has been solvothermally synthesized and characterized by single-crystal X-ray diffraction, FTIR, elemental analysis, and thermogravimetric analysis. Compound I crystallizes in monoclinic system, space group P2(1)/n with a = 8.042(2) angstrom, b = 20.004(4) angstrom, c = 10.103(2) angstrom, and beta = 90.42(3)degrees. The anionic [B7O10(OH)(3)]n(2n-) layers are interlinked via hydrogen bonding to form a 3D supramolecular network containing large channels, in which the templated [H3N(CH2)(6)NH3](2+) cations are located. (C) 2007 Elsevier Inc. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000249186100006 |
出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
源URL | [http://ir.iccas.ac.cn/handle/121111/61797] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Li, Guobao |
作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, BNLMS, Beijing 100871, Peoples R China 2.China Univ Geosci, Xray Lab, Beijing 100083, Peoples R China |
推荐引用方式 GB/T 7714 | Yang, Sihai,Li, Guobao,Tian, Shujian,et al. Synthesis and structure of a 1,6-hexyldiamine heptaborate, [H3N(CH2)(6)NH3][B7O10(OH)(3)][J]. JOURNAL OF SOLID STATE CHEMISTRY,2007,180(8):2225-2232. |
APA | Yang, Sihai,Li, Guobao,Tian, Shujian,Lia, Fuhui,Xiong, Ming,&Lin, Jianhua.(2007).Synthesis and structure of a 1,6-hexyldiamine heptaborate, [H3N(CH2)(6)NH3][B7O10(OH)(3)].JOURNAL OF SOLID STATE CHEMISTRY,180(8),2225-2232. |
MLA | Yang, Sihai,et al."Synthesis and structure of a 1,6-hexyldiamine heptaborate, [H3N(CH2)(6)NH3][B7O10(OH)(3)]".JOURNAL OF SOLID STATE CHEMISTRY 180.8(2007):2225-2232. |
入库方式: OAI收割
来源:化学研究所
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