Synthesis, structures and optical power limiting of some transition metal and lanthanide monoporphyrinate complexes containing electron-rich diphenylamino substituents
文献类型：期刊论文
| 作者 | Fu, Shitao; Zhu, Xunjin; Zhou, Guijiang; Wong, Wai-Yeung; Ye, Cheng; Wong, Wai-Kwok; Li, Zaoying |
| 刊名 | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
 |
| 出版日期 | 2007-05-01 |
| 期号 | 14页码:2004-2013 |
| 关键词 | Lanthanides Optical Limiting Photoluminescence Porphyrins Transition Metals |
| ISSN号 | 1434-1948 |
| DOI | 10.1002/ejic.200601190 |
| 英文摘要 | Transition metal and lanthanide monoporphyrinate complexes based on 5,10,15,20-tetrakis[p-(diphenylamino)phenyl]-21H,23H-porphine (H(2)tdpapp) have been synthesized and characterized and the X-ray crystal structures of the palladium and platinum analogues [M(tdpapp)] (M = Pd, Pt) determined. Experimental investigations of the nonlinear optical transmittance characteristics at 532 nm show that most of these new metalated porphyrinate complexes are excellent optical limiters with performances comparable or superior to those of the benchmark reverse saturable absorption dyes such as fullerene C-60 and (phthalocyanine) metal complexes. The nonlinear optical measurements reveal that the optical-limiting effects of porphyrins can be enhanced greatly by incorporation of lanthanide ions and covalent attachment of the electron-donating diphenylamino moieties to the parent porphyrinate ring. The optical-limiting thresholds for these lanthanide monoporphyrinate complexes range from 0.09 to 0.30 J cm(-2) at 82% linear transmittance, which makes them attractive candidates as optical-limiting materials for the protection of various optical devices. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007). |
| 语种 | 英语 |
| WOS记录号 | WOS:000246655100007 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/61831]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wong, Wai-Kwok |
| 作者单位 | 1.Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China 2.Hong Kong Baptist Univ, Ctr Adv Luminescence Mat, Kowloon Tong, Hong Kong, Peoples R China 3.Wuhan Univ, Dept Chem, Wuhan 430072, Hubei, Peoples R China 4.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fu, Shitao,Zhu, Xunjin,Zhou, Guijiang,et al. Synthesis, structures and optical power limiting of some transition metal and lanthanide monoporphyrinate complexes containing electron-rich diphenylamino substituents[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2007(14):2004-2013. |
| APA | Fu, Shitao.,Zhu, Xunjin.,Zhou, Guijiang.,Wong, Wai-Yeung.,Ye, Cheng.,...&Li, Zaoying.(2007).Synthesis, structures and optical power limiting of some transition metal and lanthanide monoporphyrinate complexes containing electron-rich diphenylamino substituents.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(14),2004-2013. |
| MLA | Fu, Shitao,et al."Synthesis, structures and optical power limiting of some transition metal and lanthanide monoporphyrinate complexes containing electron-rich diphenylamino substituents".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .14(2007):2004-2013. |
入库方式： OAI收割
来源：化学研究所
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