中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Effect of in situ synthesized macroactivator on morphology of PA6/PS blends via successive polymerization

文献类型:期刊论文

作者Pei, Aihua; Liu, Andong; Xie, Tingxiu; Yang, Guisheng
刊名JOURNAL OF APPLIED POLYMER SCIENCE
出版日期2007-08-15
卷号105期号:4页码:1757-1765
关键词Macroactivator Tmi Ps-g-pa6 Ps/pa6 Blends Morphology
ISSN号0021-8995
DOI10.1002/app.25650
英文摘要In situ polymerization and in situ compatibilization was adopted for preparation of ternary PA6/PS-g-PA6/PS blends by means of successive polymerization of styrene, with TMI and epsilon-caprolactam, via free radical copolymerization and anionic ring-opening polymerization, respectively. Copolymer poly(St-g-TMI), the chain of which bears isocyanate (-NCO), acts as a macroactivator to initiate PA6 chain growth from the PS chain and graft copolymer of PS-g-PA6 and pure PA6 form, simultaneously. The effect of the macroactivator poly(St-g-TMI) on the phase morphology was investigated in detail, using scanning electron microscopy. In case of blends with higher content of PS-g-PA6 copolymer, copolymer nanoparticles coexisting with the PS formed the matrix, in which PA6 microspheres were dispersed evenly as minor phase. The content of the compositions (homopolystyrene, homopolyamide 6, and PS-g-PA6) of the blends were determined by selective solvent extraction technique. The mechanical properties of PA6/PS-g-PA6/PS blends were better than that of PA6/PS blends. Especially for the blends T10 with lower PS-g-PA6 copolymer content, both the flexural strength and flexural modulus showed significantly improving because of the improved interfacial adhesion between PS and PA6. (c) 2007 Wiley Periodicals, Inc.
语种英语
WOS记录号WOS:000247576600006
出版者JOHN WILEY & SONS INC
源URL[http://ir.iccas.ac.cn/handle/121111/61853]  
专题中国科学院化学研究所
通讯作者Yang, Guisheng
作者单位1.Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Technol, Key Lab Engn Plast,Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China
3.Shanghai Genius Adv Mat Co Ltd, Shanghai 201109, Peoples R China
推荐引用方式
GB/T 7714
Pei, Aihua,Liu, Andong,Xie, Tingxiu,et al. Effect of in situ synthesized macroactivator on morphology of PA6/PS blends via successive polymerization[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2007,105(4):1757-1765.
APA Pei, Aihua,Liu, Andong,Xie, Tingxiu,&Yang, Guisheng.(2007).Effect of in situ synthesized macroactivator on morphology of PA6/PS blends via successive polymerization.JOURNAL OF APPLIED POLYMER SCIENCE,105(4),1757-1765.
MLA Pei, Aihua,et al."Effect of in situ synthesized macroactivator on morphology of PA6/PS blends via successive polymerization".JOURNAL OF APPLIED POLYMER SCIENCE 105.4(2007):1757-1765.

入库方式: OAI收割

来源:化学研究所

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