Enhancing reaction rate of transesterification of glycerol monostearate and methanol by CO2
文献类型：期刊论文
| 作者 | Song, Jiyuan; Hou, Minqiang; Jiang, Tao; Han, Buxing; Li, Xiaoyong; Liu, Gang; Yang, Guanyin |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY A
 |
| 出版日期 | 2007-11-29 |
| 卷号 | 111期号:47页码:12007-12010 |
| ISSN号 | 1089-5639 |
| DOI | 10.1021/jp0762222 |
| 英文摘要 | The effect Of CO2 as a green additive on the reaction rate of transesterification of glycerol monostearate with methanol was studied at 333.15 and 343.15 K up to 10.5 MPa. It was demonstrated that addition Of CO2 in the reaction system could increase the reaction rate significantly. The phase behavior of the CO2+methanol+ glycerol monostearate ternary system was also determined at 333.15 and 343.15 K. It is shown that addition Of CO2 can enhance the miscibility of the reactant. The main reasons for the reaction rate enhancement are that CO2 can enhance the miscibility of the reactants, reduce the viscosity of the reaction mixture, and increase the diffusion coefficients of the reactants. |
| 语种 | 英语 |
| WOS记录号 | WOS:000251140700009 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/61909]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Han, Buxing |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, Jiyuan,Hou, Minqiang,Jiang, Tao,et al. Enhancing reaction rate of transesterification of glycerol monostearate and methanol by CO2[J]. JOURNAL OF PHYSICAL CHEMISTRY A,2007,111(47):12007-12010. |
| APA | Song, Jiyuan.,Hou, Minqiang.,Jiang, Tao.,Han, Buxing.,Li, Xiaoyong.,...&Yang, Guanyin.(2007).Enhancing reaction rate of transesterification of glycerol monostearate and methanol by CO2.JOURNAL OF PHYSICAL CHEMISTRY A,111(47),12007-12010. |
| MLA | Song, Jiyuan,et al."Enhancing reaction rate of transesterification of glycerol monostearate and methanol by CO2".JOURNAL OF PHYSICAL CHEMISTRY A 111.47(2007):12007-12010. |
入库方式： OAI收割
来源：化学研究所
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