New series of indium formates: Hydrothermal synthesis, structure and coordination modes
文献类型：期刊论文
| 作者 | Jie Su; Yingxia Wang; Sihai Yang; Guobao Li; Fuhui Liao; Jianhua Lin |
| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2007-10-01 |
| 卷号 | 46期号:20页码:8403-8409 |
| ISSN号 | 0020-1669 |
| DOI | 10.1021/ic7007599 |
| 英文摘要 | Three new indium(III) compounds, ln(HCOO)(3) (1), ln(2)(HCOO)(5)(OH) (2), and ln(HCOO)(2)(OH) (3), were synthesized under hydrothermal conditions and characterized by single crystal and powder X-ray diffraction experiments, as well as by IR spectroscopy, elemental analysis, and coupled TG-DSC-MS measurement. All of these compounds adopt 3D framework structures consisting of InO6 octahedra and the 2.11 binding modes of formate with the (syn, syn-; syn, anti-; anti, anti-) configurations. The structural investigation of these indium formates reveals that the gradual introduction of the hydroxyl groups into the structures induces the polymerization of the InO6 octahedra, that is, InO6 is isolated in 1, becomes dimeric in 2, and finally forms 1 D chains in 3. In addition, a simple formula that may be used for estimating the overall coordination number of the formate in M-a(HCOO)(b)L-c is proposed. |
| 语种 | 英语 |
| 出版者 | AMER CHEMICAL SOC |
| WOS记录号 | WOS:000249698700039 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/61923]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yingxia Wang |
| 作者单位 | Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jie Su,Yingxia Wang,Sihai Yang,et al. New series of indium formates: Hydrothermal synthesis, structure and coordination modes[J]. INORGANIC CHEMISTRY,2007,46(20):8403-8409. |
| APA | Jie Su,Yingxia Wang,Sihai Yang,Guobao Li,Fuhui Liao,&Jianhua Lin.(2007).New series of indium formates: Hydrothermal synthesis, structure and coordination modes.INORGANIC CHEMISTRY,46(20),8403-8409. |
| MLA | Jie Su,et al."New series of indium formates: Hydrothermal synthesis, structure and coordination modes".INORGANIC CHEMISTRY 46.20(2007):8403-8409. |
入库方式： OAI收割
来源：化学研究所
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