中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Stereocomplexation and monolayer morphologies of a stereoregular poly(methyl methacrylate) mixture formed at the air/water surface

文献类型:期刊论文

作者Liu, Jing; Zhang, Ying; Zhang, Jianming; Shen, Deyan; Guo, Qipeng; Takahashi, Isao; Yan, Shouke
刊名JOURNAL OF PHYSICAL CHEMISTRY C
出版日期2007-05-03
卷号111期号:17页码:6488-6494
ISSN号1932-7447
DOI10.1021/jp0704564
英文摘要The stereocomplexation of stereoregular PMMA at the air/water interface was proved by structure determination using reflection-absorption IR and grazing incidence X-ray diffraction. Morphological studies on LB films of i- and s-PMMA blends with different ratios help to disclose the stereocomplexation process of stereoregular PMMA at the air/water interface. It was found that the stereocomplexes exist in particle aggregates randomly dispersed at the air/water interface. In the systems with the i:s ratio deviated from 1:2, the molecules, either i-PMMA or s-PMMA, that do not participate in the stereocomplexation build separate layer surrounding the stereocomplexes. This layer is much thinner than the particle aggregates of the stereocomplexes. If the i-PMMA molecules are rich in this thinner layer, crystallization of i-PMMA takes place, which generates lamellar structure besides the stereocomplexes.
语种英语
WOS记录号WOS:000245954900050
出版者AMER CHEMICAL SOC
源URL[http://ir.iccas.ac.cn/handle/121111/61957]  
专题中国科学院化学研究所
通讯作者Yan, Shouke
作者单位1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, State Key Lab Polymer Phys & Chem, Inst Chem, Beijing 100080, Peoples R China
2.Deakin Univ, Ctr Mat & Fibre Innovat, Geelong, Vic 3217, Australia
3.Kwansei Gakuin Univ, Dept Phys, Sch Sci & Technol, Sanda, Hyogo 6691337, Japan
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Liu, Jing,Zhang, Ying,Zhang, Jianming,et al. Stereocomplexation and monolayer morphologies of a stereoregular poly(methyl methacrylate) mixture formed at the air/water surface[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2007,111(17):6488-6494.
APA Liu, Jing.,Zhang, Ying.,Zhang, Jianming.,Shen, Deyan.,Guo, Qipeng.,...&Yan, Shouke.(2007).Stereocomplexation and monolayer morphologies of a stereoregular poly(methyl methacrylate) mixture formed at the air/water surface.JOURNAL OF PHYSICAL CHEMISTRY C,111(17),6488-6494.
MLA Liu, Jing,et al."Stereocomplexation and monolayer morphologies of a stereoregular poly(methyl methacrylate) mixture formed at the air/water surface".JOURNAL OF PHYSICAL CHEMISTRY C 111.17(2007):6488-6494.

入库方式: OAI收割

来源:化学研究所

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