Synthesis, characterization and thermostability of IIB group transition metal complexes with dithiocarbamate
文献类型：期刊论文
| 作者 | Deng Yu-Heng1; Liu Juan1; Li Ning1; Yang Yong-Li1; Ma Hong-Wei2 |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2007-12-28 |
| 卷号 | 65期号:24页码:2868-2874 |
| 关键词 | Iib Group Transition Metal Dithiocarbamate Metal-thiolate Complex Crystal Structure Thermogravimetric Analysis |
| ISSN号 | 0567-7351 |
| 英文摘要 | A series of IIB group metal Zn(II), Cd(II) complexes with dithiocarbamate (dtc) ligand (HOCH2CH2)(2)dtc. have been synthesized in methanol solution. All the complexes M[(HOCH2CH2)(2)dtc](2)L [M = Zn (1), Cd (2); L = 2,2'-bipyridyl; M = Zn (3), Cd (4), L = 1,10-phenanthroline] were characterized by IR spectra, elemental analysis and TGA. The TGA results show that all the final thermolysis residues of the above complexes are their respective metal oxides. Compounds 1 and 2 were also determined by single crystal X-ray diffraction analysis. The complex 1 crystallizes in a monoclinic system with space group P2(1)/c and parameters a=0.72146(5) nm, b=2.61720(18) nm, c=1.59438(11) nm, beta=97.899(2)degrees, V=2.9820(4) nm, Z=4, mu=1.133 mm(-1), D-c=1.297 Mg.m(-3). The complex 2 crystallizes in a triclinic system with space group P-1, and parameters a=1.0075(2) nm, b=1.1580(2) nm, c=1.1777(2) nm, alpha=70.92(3)degrees, beta= 85.71(3)degrees, gamma = 81.02(3)degrees, V= 1.2822(4) nm(3), Z= 2, mu= 2.118 mm(-1), D-c = 1.630 Mg.m(-3). |
| 语种 | 英语 |
| WOS记录号 | WOS:000252479000012 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/62027]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Deng Yu-Heng |
| 作者单位 | 1.Capital Normal Univ, Dept Chem, Beijing 100037, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Deng Yu-Heng,Liu Juan,Li Ning,et al. Synthesis, characterization and thermostability of IIB group transition metal complexes with dithiocarbamate[J]. ACTA CHIMICA SINICA,2007,65(24):2868-2874. |
| APA | Deng Yu-Heng,Liu Juan,Li Ning,Yang Yong-Li,&Ma Hong-Wei.(2007).Synthesis, characterization and thermostability of IIB group transition metal complexes with dithiocarbamate.ACTA CHIMICA SINICA,65(24),2868-2874. |
| MLA | Deng Yu-Heng,et al."Synthesis, characterization and thermostability of IIB group transition metal complexes with dithiocarbamate".ACTA CHIMICA SINICA 65.24(2007):2868-2874. |
入库方式： OAI收割
来源：化学研究所
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