Synthesis, properties, and gas permeation performance of cardo poly(arylene ether sulfone)s containing phthalimide side groups
文献类型：期刊论文
| 作者 | Chen, Guang; Zhang, Xiaosa; Zhang, Suobo; Chen, Tianlu; Wul, Yonglie |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2007-11-15 |
| 卷号 | 106期号:4页码:2808-2816 |
| 关键词 | Poly(Arylene Ether Sulfone)s Gas Permeation Phthalimide Cardo Synthesis |
| ISSN号 | 0021-8995 |
| DOI | 10.1002/app.26930 |
| 英文摘要 | Novel bisphenol monomers (1a-d) containing phthalimide groups were synthesized by the reaction of phenolphthalein with ammonia, methylamine, aniline, and 4-tert-butylanilne, respectively. A series of cardo poly (arylene ether sulfone)s was synthesized via aromatic nucleophilic substitution of 1a-d with dichlorodiphenylsulfone, and characterized in terms of thermal, mechanical and gas transport properties to H-2, O-2, N-2, and CO2. The polymers showed high glass transition temperature in the range 230-296 degrees C, good solubility in polar solvents as well as excellent thermal stability with 5% weight loss above 410 degrees C. The most permeable membrane studied showed permeability coefficients of 1.78 barrers to O-2 and 13.80 barrers to CO2, with ideal selectivity. factors of 4.24 for O-2/N-2 pair and 28.75 for CO2/CH4 pair. Furthermore, the structure-property relationship among these cardo poly(arylene ether sulfone)s had been discussed on solubility, thermal stability, mechanical, and gas permeation properties. The results indicated that introducing 4-tert-butylphenyl group improved the gas permeability of polymers evidently. (c) 2007 Wiley Periodicals, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000249590700085 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/62103]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Suobo |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Changchun 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Guang,Zhang, Xiaosa,Zhang, Suobo,et al. Synthesis, properties, and gas permeation performance of cardo poly(arylene ether sulfone)s containing phthalimide side groups[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2007,106(4):2808-2816. |
| APA | Chen, Guang,Zhang, Xiaosa,Zhang, Suobo,Chen, Tianlu,&Wul, Yonglie.(2007).Synthesis, properties, and gas permeation performance of cardo poly(arylene ether sulfone)s containing phthalimide side groups.JOURNAL OF APPLIED POLYMER SCIENCE,106(4),2808-2816. |
| MLA | Chen, Guang,et al."Synthesis, properties, and gas permeation performance of cardo poly(arylene ether sulfone)s containing phthalimide side groups".JOURNAL OF APPLIED POLYMER SCIENCE 106.4(2007):2808-2816. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。