A highly fluorescent anthracene-containing hybrid material exhibiting tunable blue-green emission based on the formation of an unusual 'IT-shaped" excimer
文献类型：期刊论文
| 作者 | Zhang, Guoqi; Yang, Guoqiang; Wang, Shuangqing; Chen, Qingqi; Ma, Jin Shi |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2007 |
| 卷号 | 13期号:13页码:3630-3635 |
| 关键词 | Anthracene Excimers Fluorescence Sensors Water Chemistry |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.200600514 |
| 英文摘要 | A series of flexible bis(9-anthryldiamine) ligands (L1-L3) linked with alkyl spacers of different chain length was synthesized and characterized, in order to investigate the coordination behavior of these diamine ligands with metal ions (Zn2+, etc.) based on fluorescence measurements. The results showed that, in the case of anthryldiamine ligands bearing two- or four-carbon links, the zinc ion induced a chelation-enhanced fluorescence (CHEF) effect in aqueous media, while a trace amount of water could selectively quench the blue emission of the Zn-II complex with a three-carbon-linked ligand (1). Meanwhile, the introduction of more water (concentration > 11 %) resulted in the formation of a new green luminescent species; the luminescence intensity was enhanced stepwise to a maximum with addition of approximately 30% water in THF solution. The peak position (centered at approximately 500 nm) and the life-time measurement (tau=19.59ns) indicated that the green luminescence was attributable to a novel edge-to-face dimeric conformation ("T-shaped" conformation) of anthracene, and not to the more common face-to-face dimeric conformation. Accordingly, H-1 NMR spectroscopic studies in nonaqueous or aqueous solution confirmed this T-shaped conformation, which is consistent with the results of single-crystal Xray structure analysis and solid-state photoluminescence studies. |
| 语种 | 英语 |
| WOS记录号 | WOS:000246434300005 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/62111]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, Guoqiang |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Photochem, Beijing 100080, Peoples R China 2.Biomarin Pharmaceut Inc, Novato, CA 94949 USA |
| 推荐引用方式 GB/T 7714 | Zhang, Guoqi,Yang, Guoqiang,Wang, Shuangqing,et al. A highly fluorescent anthracene-containing hybrid material exhibiting tunable blue-green emission based on the formation of an unusual 'IT-shaped" excimer[J]. CHEMISTRY-A EUROPEAN JOURNAL,2007,13(13):3630-3635. |
| APA | Zhang, Guoqi,Yang, Guoqiang,Wang, Shuangqing,Chen, Qingqi,&Ma, Jin Shi.(2007).A highly fluorescent anthracene-containing hybrid material exhibiting tunable blue-green emission based on the formation of an unusual 'IT-shaped" excimer.CHEMISTRY-A EUROPEAN JOURNAL,13(13),3630-3635. |
| MLA | Zhang, Guoqi,et al."A highly fluorescent anthracene-containing hybrid material exhibiting tunable blue-green emission based on the formation of an unusual 'IT-shaped" excimer".CHEMISTRY-A EUROPEAN JOURNAL 13.13(2007):3630-3635. |
入库方式： OAI收割
来源：化学研究所
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