Influence of chemical structure and polymerizaion conditions on chiroptical properties of bulky vinyl polymers
文献类型：期刊论文
| 作者 | Cao Hongqing; Liu Anhua; Yu Zhenning; Zhang Jie; Wan Xinhua; Chen Xiaofang; Zhou Qifeng |
| 刊名 | ACTA POLYMERICA SINICA
 |
| 出版日期 | 2007-10-01 |
| 期号 | 10页码:999-1005 |
| 关键词 | Para-terphenyl Helical Structure Chirality Chiroptical Property Free Radical Polymerization Reactivity Vinyl Polymer |
| ISSN号 | 1000-3304 |
| 英文摘要 | Three chiral bulky vinyl monomers, (+)-4,4"-bis[(S)-2-methylbutoxyl-2'-vinyl-para-terphenyl(pBMVT),( +)-3, 3"-bis[(S)-2-methylbutoxyl]-2'-viny]-para-terphenyl ( m-BMVT) and ( +)-2, 2"-bis[(S)-2-methylbutoxy 1 -2'- vinyl-para-terphenyl (o-BMVT) were synthesized. The later two were new molecules. The dependence of polymerizabilities of monomers on the chemical structures and the dependence of chiroptical properties of polymers on the chemical structures and reaction conditions were systematically studied. p-BMVT and m-BMVT were readily polymerized by radical mechanism to produce optically active helical polymers. Moving the chiral alkoxy groups on terphenyl by just a distance of one bond length inversed the direction of optical rotation. o-BMVT was obtained with quite low yield and couldn't undergo radical polymerization. Using polar aromatic solvent and apolar aliphatic solvent, increasing reaction temperature, and reducing monomer concentration favored the formation of polymers with higher specific optical rotation. |
| 语种 | 英语 |
| WOS记录号 | WOS:000250566100016 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/62197]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wan Xinhua |
| 作者单位 | Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Minist Educ,Key Lab Polymer Chem & Phys, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cao Hongqing,Liu Anhua,Yu Zhenning,et al. Influence of chemical structure and polymerizaion conditions on chiroptical properties of bulky vinyl polymers[J]. ACTA POLYMERICA SINICA,2007(10):999-1005. |
| APA | Cao Hongqing.,Liu Anhua.,Yu Zhenning.,Zhang Jie.,Wan Xinhua.,...&Zhou Qifeng.(2007).Influence of chemical structure and polymerizaion conditions on chiroptical properties of bulky vinyl polymers.ACTA POLYMERICA SINICA(10),999-1005. |
| MLA | Cao Hongqing,et al."Influence of chemical structure and polymerizaion conditions on chiroptical properties of bulky vinyl polymers".ACTA POLYMERICA SINICA .10(2007):999-1005. |
入库方式： OAI收割
来源：化学研究所
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