中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis and characterization of phosphor and nitrogen co-doped titania

文献类型:期刊论文

作者Lin, L.; Zheng, R. Y.; Xie, J. L.; Zhu, Y. X.; Xie, Y. C.
刊名APPLIED CATALYSIS B-ENVIRONMENTAL
出版日期2007-10-30
卷号76期号:1-2页码:196-202
关键词Titania Phosphor Nitrogen Photocatalysis 4-chlorophenol (4cp)
ISSN号0926-3373
DOI10.1016/j.apcatb.2007.05.023
英文摘要Phosphor and nitrogen co-doped titania were prepared by a simple modified sol-gel method with hypophosphorous acid and ammonia as the P and N sources, respectively. The resulting materials were characterized by X-ray diffraction (XRD), nitrogen physical adsorption at 77 K, Fourier transformed infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), and UV-vis spectroscopy. It was found that modification by phosphor could retard the phase transformation of anatase to rutile and increase the surface area significantly, while the doped nitrogen had little influence on the thermal stability and texture of the titania. The chemical nature of N and P was identified by XPS as N-Ti-O and Ti-O-P in the anatase TiO2 lattice. UV-vis spectra showed that modification by phosphor or nitrogen extended the spectral response of Titania into the visible region. The photocatalytic activity of titania modified by only nitrogen was limited, much lower than that of phosphor-doped titania. However, when titania was co-doped with both phosphor and nitrogen, the photocatalytic activity was further enhanced efficiently. (C) 2007 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000250799700023
出版者ELSEVIER SCIENCE BV
源URL[http://ir.iccas.ac.cn/handle/121111/62221]  
专题中国科学院化学研究所
通讯作者Zhu, Y. X.
作者单位Peking Univ, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
推荐引用方式
GB/T 7714
Lin, L.,Zheng, R. Y.,Xie, J. L.,et al. Synthesis and characterization of phosphor and nitrogen co-doped titania[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2007,76(1-2):196-202.
APA Lin, L.,Zheng, R. Y.,Xie, J. L.,Zhu, Y. X.,&Xie, Y. C..(2007).Synthesis and characterization of phosphor and nitrogen co-doped titania.APPLIED CATALYSIS B-ENVIRONMENTAL,76(1-2),196-202.
MLA Lin, L.,et al."Synthesis and characterization of phosphor and nitrogen co-doped titania".APPLIED CATALYSIS B-ENVIRONMENTAL 76.1-2(2007):196-202.

入库方式: OAI收割

来源:化学研究所

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