Synthesis and characterization of phosphor and nitrogen co-doped titania
文献类型:期刊论文
作者 | Lin, L.; Zheng, R. Y.; Xie, J. L.; Zhu, Y. X.; Xie, Y. C. |
刊名 | APPLIED CATALYSIS B-ENVIRONMENTAL
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出版日期 | 2007-10-30 |
卷号 | 76期号:1-2页码:196-202 |
关键词 | Titania Phosphor Nitrogen Photocatalysis 4-chlorophenol (4cp) |
ISSN号 | 0926-3373 |
DOI | 10.1016/j.apcatb.2007.05.023 |
英文摘要 | Phosphor and nitrogen co-doped titania were prepared by a simple modified sol-gel method with hypophosphorous acid and ammonia as the P and N sources, respectively. The resulting materials were characterized by X-ray diffraction (XRD), nitrogen physical adsorption at 77 K, Fourier transformed infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), and UV-vis spectroscopy. It was found that modification by phosphor could retard the phase transformation of anatase to rutile and increase the surface area significantly, while the doped nitrogen had little influence on the thermal stability and texture of the titania. The chemical nature of N and P was identified by XPS as N-Ti-O and Ti-O-P in the anatase TiO2 lattice. UV-vis spectra showed that modification by phosphor or nitrogen extended the spectral response of Titania into the visible region. The photocatalytic activity of titania modified by only nitrogen was limited, much lower than that of phosphor-doped titania. However, when titania was co-doped with both phosphor and nitrogen, the photocatalytic activity was further enhanced efficiently. (C) 2007 Elsevier B.V. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000250799700023 |
出版者 | ELSEVIER SCIENCE BV |
源URL | [http://ir.iccas.ac.cn/handle/121111/62221] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Zhu, Y. X. |
作者单位 | Peking Univ, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Lin, L.,Zheng, R. Y.,Xie, J. L.,et al. Synthesis and characterization of phosphor and nitrogen co-doped titania[J]. APPLIED CATALYSIS B-ENVIRONMENTAL,2007,76(1-2):196-202. |
APA | Lin, L.,Zheng, R. Y.,Xie, J. L.,Zhu, Y. X.,&Xie, Y. C..(2007).Synthesis and characterization of phosphor and nitrogen co-doped titania.APPLIED CATALYSIS B-ENVIRONMENTAL,76(1-2),196-202. |
MLA | Lin, L.,et al."Synthesis and characterization of phosphor and nitrogen co-doped titania".APPLIED CATALYSIS B-ENVIRONMENTAL 76.1-2(2007):196-202. |
入库方式: OAI收割
来源:化学研究所
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