Peanut-shaped aggregation of CaCO3 crystallites in the presence of an amphiphilic derivative of carboxymethylchitosan
文献类型：期刊论文
| 作者 | Huang, Yaping; Shen, Qiang; Sui, Weiping; Guo, Meili; Zhao, Ying; Wang, Dujin; Xu, Duanfu |
| 刊名 | COLLOID AND POLYMER SCIENCE
 |
| 出版日期 | 2007-03-01 |
| 卷号 | 285期号:6页码:641-647 |
| 关键词 | Calcim Carbonate Crystallization Chitosan Derivative Template Effect Peanut-shaped Aggregates |
| ISSN号 | 0303-402X |
| DOI | 10.1007/s00396-006-1606-4 |
| 英文摘要 | An amphiphilic derivative of carboxymethylchitosan (CMCS), (2-hydroxyl-3-butoxyl)propyl-CMCS (HBP-CMCS), was used as an organic additive in the precipitation process of calcium carbonate (CaCO3). HBP-CMCS molecules can interact with calcium ions, the functional groups of which act as active sites for the nucleation and crystallization of CaCO3. Simultaneously, HBP-CMCS molecule also functionalizes as a colloidal stabilizer to prohibit the sedimentation of the grown CaCO3 crystals, depending upon the molar ratio of the initial Ca2+ ions to the repeat units of HBP-CMCS molecules. The combination investigations of scanning electron microscopy, X-ray diffraction, and Fourier transform infrared spectroscopy on the precipitated CaCO3 crystals proved that concentrations of HBP-CMCS and Ca2+ exert great influence on the crystallization habit of CaCO3, such as the nucleation, growth, morphology, crystal form, etc. The formation of the peanut-shaped CaCO3 particles suggests the template effect of HBP-CMCS molecules on the aggregation behavior of CaCO3 nanocrystals. |
| 语种 | 英语 |
| WOS记录号 | WOS:000244780600004 |
| 出版者 | SPRINGER |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/62279]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Dujin |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China 2.Shandong Univ, Key Lab Colloid & Interface Chem, Educ Minist, Jinan 250100, Peoples R China 3.Beijing Univ Aeronaut & Astronaut, Dept Mat Sci & Engn, Beijing 100083, Peoples R China 4.Univ Jinan, Sch Chem & Chem Engn, Jinan 250022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Yaping,Shen, Qiang,Sui, Weiping,et al. Peanut-shaped aggregation of CaCO3 crystallites in the presence of an amphiphilic derivative of carboxymethylchitosan[J]. COLLOID AND POLYMER SCIENCE,2007,285(6):641-647. |
| APA | Huang, Yaping.,Shen, Qiang.,Sui, Weiping.,Guo, Meili.,Zhao, Ying.,...&Xu, Duanfu.(2007).Peanut-shaped aggregation of CaCO3 crystallites in the presence of an amphiphilic derivative of carboxymethylchitosan.COLLOID AND POLYMER SCIENCE,285(6),641-647. |
| MLA | Huang, Yaping,et al."Peanut-shaped aggregation of CaCO3 crystallites in the presence of an amphiphilic derivative of carboxymethylchitosan".COLLOID AND POLYMER SCIENCE 285.6(2007):641-647. |
入库方式： OAI收割
来源：化学研究所
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