Steady-state and time-resolved spectroscopic studies on the interaction between TMPyP4 and nucleic acids
文献类型：期刊论文
| 作者 | Wang Xue-Fei; Mang Hui-Juan; Wu Yi-Shi; Wang Peng; Ai Xi-Cheng; Zhang Jian-Ping |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2007-07-01 |
| 卷号 | 28期号:7页码:1350-1355 |
| 关键词 | Porphyrin Nucleic Acid Binding Constant Spectroscopy |
| ISSN号 | 0251-0790 |
| 英文摘要 | Steady-state absorption and fluorescence, circular dichroism and picosecond time-resolved fluorescence spectroscopies were used to investigate the interaction between 5, 10, 15, 20-tetrakis ( 4-N-methylpyridine)porphyrin (TMPyP4) and nucleic acid molecules, i. e. bases (A, G, T, C), deoxynucleosides (dA, dG, dT, dC), deoxynucleotides (dAMP, dGMP, dTMP, dCMP) and oligonucleotides ( dA,, dG,, dT,, dC,). The results show that the interactions between TMPyP4 and the purine species were stronger than that between TMPyP4 and the pyrimidine species. For a certain series of species, such as A, dA, dAMP and dA(6) the interaction strength follows the order: base-nucleoside < nucleotide < oligonucleotide. Except for the G series, the TMPyP4-nucleic acid complexes exhibit a fast ( 1-2 ns) and a slow( about 10 ns) decay component, reflecting the influence from the exciplex and that from the low dielectric constant of the TMPyP4 surroundings, respectively. Oligonucleotides are able to induce the circular dichroism of TMPyP4 in its Soret-band spectral region, whereas all of the monomeric nucleic acids cannot do so. |
| 语种 | 英语 |
| WOS记录号 | WOS:000248202500036 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/62301]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang Xue-Fei |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 2.Renmin Univ China, Coll Sci, Dept Chem, Beijing 100872, Peoples R China 3.Beijing Inst Technol, Sch Life Sci & Technol, Beijing 100081, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang Xue-Fei,Mang Hui-Juan,Wu Yi-Shi,et al. Steady-state and time-resolved spectroscopic studies on the interaction between TMPyP4 and nucleic acids[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2007,28(7):1350-1355. |
| APA | Wang Xue-Fei,Mang Hui-Juan,Wu Yi-Shi,Wang Peng,Ai Xi-Cheng,&Zhang Jian-Ping.(2007).Steady-state and time-resolved spectroscopic studies on the interaction between TMPyP4 and nucleic acids.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,28(7),1350-1355. |
| MLA | Wang Xue-Fei,et al."Steady-state and time-resolved spectroscopic studies on the interaction between TMPyP4 and nucleic acids".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 28.7(2007):1350-1355. |
入库方式： OAI收割
来源：化学研究所
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