Water-resistant conducting hybrids from electrostatic interactions
文献类型：期刊论文
| 作者 | Luo, Jing; Wang, Qiguan; Wang, Xianhong; Li, Ji; Zhao, Xiaojiang; Wang, Fosong |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
 |
| 出版日期 | 2007-04-15 |
| 卷号 | 45期号:8页码:1424-1431 |
| 关键词 | Compatibility Conducting Polymers Electrostatic Interactions Polyaniline Sol-gel |
| ISSN号 | 0887-624X |
| DOI | 10.1002/pola.21912 |
| 英文摘要 | Conductive hybrids were prepared in a water/ethanol solution via the Solgel process from an inorganic sol containing carboxyl groups and water-borne conductive polyaniline (cPANI). The inorganic sol was prepared by the hydrolysis and condensation of methyltriethoxysilane with the condensed product of maleic anhydride and aminopropyltriethoxysilane as a catalyst, for which the carboxyl counterion along the cPANI backbone acted as an electrostatic-interaction moiety. The existence of this electrostatic interaction could improve the compatibility of the two components and contribute to the homogeneous dispersion of cPANI in the silica phase. The electrostaticinteraction hybrids displayed a conductivity percolation threshold as low as 1.1 wt % polyaniline in an emeraldine base, showing 2 orders of magnitude higher electrical conductivity than that without electrostatic interactions. The electrostatic-interaction hybrids also showed good water resistance; the electrical conductivity with a cPANI loading of 16 wt % underwent a slight change after 14 days of soaking in water. (c) 2006 Wiley Periodicals, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000245347100006 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/62309]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Xianhong |
| 作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, Grad Sch, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Luo, Jing,Wang, Qiguan,Wang, Xianhong,et al. Water-resistant conducting hybrids from electrostatic interactions[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2007,45(8):1424-1431. |
| APA | Luo, Jing,Wang, Qiguan,Wang, Xianhong,Li, Ji,Zhao, Xiaojiang,&Wang, Fosong.(2007).Water-resistant conducting hybrids from electrostatic interactions.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,45(8),1424-1431. |
| MLA | Luo, Jing,et al."Water-resistant conducting hybrids from electrostatic interactions".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 45.8(2007):1424-1431. |
入库方式： OAI收割
来源：化学研究所
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