Unsymmetric bimetal(II) complexes: Synthesis, structures and catalytic behaviors toward ethylene
文献类型：期刊论文
| 作者 | Zhang, Shu; Sun, Wen-Hua ; Kuang, Xiaofei; Vystorop, Igor; Yi, Jianjun
|
| 刊名 | JOURNAL OF ORGANOMETALLIC CHEMISTRY
 |
| 出版日期 | 2007-11-01 |
| 卷号 | 692期号:23页码:5307-5316 |
| 关键词 | Bimetal Complexes Ethylene Oligomerization Ethylene Polymerization 2-methyl-2 4-bis(6-iminopyridin-2-yl)-1h-1 5-benzodiazepines |
| ISSN号 | 0022-328X |
| DOI | 10.1016/j.jorganchem.2007.08.020 |
| 英文摘要 | A series of unsymmetric bimetal(II) (Fe, Co and Ni) complexes ligated by 2-methyl-2,4-bis(6-iminopyridin-2-yl)-1H-1,5-benzodiazepines were synthesized and characterized by IR spectra and elemental analysis, while a representative nickel(II) complex (5a) was determined by single-crystal X-ray crystallography. These iron(II) complexes were found to exhibit good activities for ethylene oligomerization and polymerization in the presence of MMAO and afforded alpha-olefins in high selectivity, and the composition of oligomers followed the Schluz-Flory distribution. The nickel(II) complexes mainly dimerize ethylene with considerable activity. The influences of coordinative ligands and reaction parameters were fully investigated on the catalytic activity and properties of these complexes. (c) 2007 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000250934800026 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/62317]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Wen-Hua |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Chem, Natl Lab Mol Sci, Beijing 100080, Peoples R China 3.PetroChina Co Ltd, Petrochem Res Inst, Beijing 100083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Shu,Sun, Wen-Hua,Kuang, Xiaofei,et al. Unsymmetric bimetal(II) complexes: Synthesis, structures and catalytic behaviors toward ethylene[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2007,692(23):5307-5316. |
| APA | Zhang, Shu,Sun, Wen-Hua,Kuang, Xiaofei,Vystorop, Igor,&Yi, Jianjun.(2007).Unsymmetric bimetal(II) complexes: Synthesis, structures and catalytic behaviors toward ethylene.JOURNAL OF ORGANOMETALLIC CHEMISTRY,692(23),5307-5316. |
| MLA | Zhang, Shu,et al."Unsymmetric bimetal(II) complexes: Synthesis, structures and catalytic behaviors toward ethylene".JOURNAL OF ORGANOMETALLIC CHEMISTRY 692.23(2007):5307-5316. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。