Synthesis, characterization, and electroluminescence of new conjugated PPV derivatives bearing triphenylamine side-chain through a vinylene bridge
文献类型：期刊论文
| 作者 | Tan, Zhan'ao1; Tang, Rupei2,3; Xi, Fu; Li, Yongfang1 |
| 刊名 | POLYMERS FOR ADVANCED TECHNOLOGIES
 |
| 出版日期 | 2007-12-01 |
| 卷号 | 18期号:12页码:963-970 |
| 关键词 | Poly(P-phenylene Vinylene) Polymer Light-emitting Diodes Electroluminescence |
| ISSN号 | 1042-7147 |
| DOI | 10.1002/pat.928 |
| 英文摘要 | Three new conjugated poly(p-phenylene vinylene) (PPV) derivatives bearing triphenylamine side-chain through a vinylene bridge, poly(2-(4 '-(diphenylamino)phenylenevinyl)-1,4-phenylenevinylene) (DP-PPV), poly(2-(3 '-(3 '',7 ''-dimethyloctyloxy)phenyl)-1,4-phenylenevinylene-alt-2-(4 '-(diphenylamino)phenylenevinyl)-1,4-phenylenevinylene) (DODP-PPV), and poly(2-(4 '-(diphenylamino)phenylenevinyl)-1,4-phenylenevinylene-co-2-(3 ',5 '-bis(3 '',7 ''-dimethyloctyloxy)-1,4-phenylenevinylene) (DP-co-BD-PPV), were synthesized according to the Gilch Or Wittig method. Among the three polymers, the copolymer DP-co-BD-PPV is soluble in common solvents with good thermal stability with 5% weight loss at temperatures higher than 386 degrees C. The weight-average molecular weight (M-w) and polydispersity index (PDI) of DP-co-BD-PPV were 1.83 X 10(5) and 2.33, respectively. The single-layer polymer light-emitting diodes (PLEDs) with the configuration of Indium tin oxide (ITO)/poly (3,4-ethylenedioxythiophene): poly(4-styrene sulfonate)(PEDOT:PSS)/DP-co-BD-PPV/Ca/Al were fabricated. The PLED emitted yellow-green light with the turn-on voltage of ca. 4.9 V, the maximum luminance of ca. 990 cd/m(2) at 15.8 V, and the maximum electroluminescence (EL) efficiency of 0.22 cd/A. Copyright (c) 2007 John Wiley & Sons, Ltd. |
| 语种 | 英语 |
| WOS记录号 | WOS:000252461500003 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/62371]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xi, Fu |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, CAS Lab Organ Solids, Beijing 100080, Peoples R China 2.Wuhan Univ Technol, Dept Chem Engn, Beijing Natl Lab Mol Sci, Wuhan 430070, Peoples R China 3.Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tan, Zhan'ao,Tang, Rupei,Xi, Fu,et al. Synthesis, characterization, and electroluminescence of new conjugated PPV derivatives bearing triphenylamine side-chain through a vinylene bridge[J]. POLYMERS FOR ADVANCED TECHNOLOGIES,2007,18(12):963-970. |
| APA | Tan, Zhan'ao,Tang, Rupei,Xi, Fu,&Li, Yongfang.(2007).Synthesis, characterization, and electroluminescence of new conjugated PPV derivatives bearing triphenylamine side-chain through a vinylene bridge.POLYMERS FOR ADVANCED TECHNOLOGIES,18(12),963-970. |
| MLA | Tan, Zhan'ao,et al."Synthesis, characterization, and electroluminescence of new conjugated PPV derivatives bearing triphenylamine side-chain through a vinylene bridge".POLYMERS FOR ADVANCED TECHNOLOGIES 18.12(2007):963-970. |
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来源：化学研究所
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