Study of the morphology of poly(butylene succinate)/poly(ethylene oxide) blends using hot-stage atomic force microscopy
文献类型：期刊论文
| 作者 | Wang, Haijun; Schultz, Jerold M.; Yan, Shouke |
| 刊名 | POLYMER
 |
| 出版日期 | 2007-06-04 |
| 卷号 | 48期号:12页码:3530-3539 |
| 关键词 | Blends Crystallization Afm |
| ISSN号 | 0032-3861 |
| DOI | 10.1016/j.polymer.2007.03.079 |
| 英文摘要 | Blends of poly(butylene succinate) (PBS) and poly(ethylene oxide) (PEO) were cast into films, melted, and crystallized. A number of PBS/PEO blend compositions, ranging from 85/15 to 20/80 were used. The PBS, with a higher melting point, always crystallizes first, providing a scaffold on which the PEO would crystallize. AFM phase and height images were made at room temperature and at higher temperatures, as the PEO melted, allowing one to determine the morphology and location of the PEO. It was found that at low PEO concentrations (below 15 w/o) the PEO resides preferentially between PBS lamellae. This interlamellar PEO does not crystallize, except under extreme undercooling. At higher concentrations, larger amorphous domains exist within the PBS crystalline scaffold and PEO can crystallize in these domains. Two unexpected phenomena are observed: (1) the reversible exuding of PEO from interlamellar spaces to the surface for crystallization and (2) an unusual orientation of PEO lamellae within amorphous domains in the PBS scaffold. (C) 2007 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000247450100021 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/62395]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Schultz, Jerold M. |
| 作者单位 | 1.Univ Delaware, Dept Mat Sci & Engn, Newark, DE 19716 USA 2.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Haijun,Schultz, Jerold M.,Yan, Shouke. Study of the morphology of poly(butylene succinate)/poly(ethylene oxide) blends using hot-stage atomic force microscopy[J]. POLYMER,2007,48(12):3530-3539. |
| APA | Wang, Haijun,Schultz, Jerold M.,&Yan, Shouke.(2007).Study of the morphology of poly(butylene succinate)/poly(ethylene oxide) blends using hot-stage atomic force microscopy.POLYMER,48(12),3530-3539. |
| MLA | Wang, Haijun,et al."Study of the morphology of poly(butylene succinate)/poly(ethylene oxide) blends using hot-stage atomic force microscopy".POLYMER 48.12(2007):3530-3539. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。