An efficient synthesis of resveratrol and a hydroxyl derivative via the Perkin reaction: cis to trans isomerisation in a demethylation process
文献类型:期刊论文
作者 | Li, Guoxing1,2; Zou, Yong1; Zhang, Xuejing1 |
刊名 | JOURNAL OF CHEMICAL RESEARCH
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出版日期 | 2007-11-01 |
期号 | 11页码:657-659 |
关键词 | Polyphenolic Stilbenes Perkin Reaction Resveratrol Isomerisation 3 4 4 ' 5-trans-tetrahydroxystilbene |
ISSN号 | 1747-5198 |
DOI | 10.3184/030823407X266234 |
英文摘要 | Two trans polyphenolic stilbenes, Resveratrol and 3,4,4',5-trans-tetrahydroxystilbene, were prepared in three steps from 4-methoxy phenylacetic acid and methoxylated benzaldehydes via a Perkin reaction. An interesting cis to trans isomerisation occured in the demethylation process in the presence of AII(3) and acetonitrile to give resveratrol and 3,4,4',5-trans-tetrahydroxystilbene with overall yields of 51% and 48% respectively. |
语种 | 英语 |
WOS记录号 | WOS:000254178200013 |
出版者 | SCIENCE REVIEWS 2000 LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/62413] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Zou, Yong |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Guangzhou 510650, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Guoxing,Zou, Yong,Zhang, Xuejing. An efficient synthesis of resveratrol and a hydroxyl derivative via the Perkin reaction: cis to trans isomerisation in a demethylation process[J]. JOURNAL OF CHEMICAL RESEARCH,2007(11):657-659. |
APA | Li, Guoxing,Zou, Yong,&Zhang, Xuejing.(2007).An efficient synthesis of resveratrol and a hydroxyl derivative via the Perkin reaction: cis to trans isomerisation in a demethylation process.JOURNAL OF CHEMICAL RESEARCH(11),657-659. |
MLA | Li, Guoxing,et al."An efficient synthesis of resveratrol and a hydroxyl derivative via the Perkin reaction: cis to trans isomerisation in a demethylation process".JOURNAL OF CHEMICAL RESEARCH .11(2007):657-659. |
入库方式: OAI收割
来源:化学研究所
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