The rheological behavior and dynamic mechanical properties of syndiotactic 1,2-polybutadiene
文献类型：期刊论文
| 作者 | He, Xiaofeng; Sun, Guangping; Li, Jing; Wang, Biao; Li, Min; Liu, Jingjiang; Bi, Jifu; Jiang, Liansheng; Zhang, Xuequan |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2007-09-05 |
| 卷号 | 105期号:5页码:2468-2473 |
| 关键词 | Zero Shear Viscosity Dynamic Mechanical Properties Crosslinked Reaction Syndiotactic 1 2-polybutadience |
| ISSN号 | 0021-8995 |
| DOI | 10.1002/app.26439 |
| 英文摘要 | The rheological behavior and the dynamic mechanical properties of syndiotactic 1,2-polybutadiene (sPB) were investigated by a rotational rheometer (MCR-300) and a dynamic mechanical analyzer (DMA-242C). Rheological behavior of sPB-830, a sPB with crystalline degree of 20.1% and syndiotactic content of 65.1%, showed that storage modulus (G ') and loss modulus (G '') decreased, and the zero shear viscosity (eta(0)) decreased slightly with increasing temperature when measuring temperatures were lower than 160 degrees C. However, G ' and G '' increased at the end region of relaxation curves with increasing temperature and)10 increased with increasing temperature as the measuring temperatures were higher than 160 degrees C. Furthermore, critical crosslinked reaction temperature was detected at about 160 degrees C for sPB-830. The crosslinked reaction was not detected when test temperature was lower than 150 degrees C for measuring the dynamic mechanical properties of sample. The relationship between processing temperature and crosslinked reaction was proposed for the sPB-830 sample. (c) 2007 Wiley Periodicals, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000247943800005 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/62443]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Jingjiang |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Jilin Univ, Dept Mat Sci & Engn, Minist Educ, Key Lab Automobile Mat Minist Educ, Changchun 130025, Peoples R China 3.Tianjin Univ Sci & Technol, Coll Food Engn & Biotechnol, BioX Res Ctr, Tianjin 300457, Peoples R China |
| 推荐引用方式 GB/T 7714 | He, Xiaofeng,Sun, Guangping,Li, Jing,et al. The rheological behavior and dynamic mechanical properties of syndiotactic 1,2-polybutadiene[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2007,105(5):2468-2473. |
| APA | He, Xiaofeng.,Sun, Guangping.,Li, Jing.,Wang, Biao.,Li, Min.,...&Zhang, Xuequan.(2007).The rheological behavior and dynamic mechanical properties of syndiotactic 1,2-polybutadiene.JOURNAL OF APPLIED POLYMER SCIENCE,105(5),2468-2473. |
| MLA | He, Xiaofeng,et al."The rheological behavior and dynamic mechanical properties of syndiotactic 1,2-polybutadiene".JOURNAL OF APPLIED POLYMER SCIENCE 105.5(2007):2468-2473. |
入库方式： OAI收割
来源：化学研究所
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