Synthesis of novel functional polyolefin containing carboxylic acid via Friedel-Crafts acylation reaction
文献类型：期刊论文
| 作者 | Zheng, Yi; Li, Yanguo; Pan, Li; Li, Yuesheng |
| 刊名 | POLYMER
 |
| 出版日期 | 2007-04-24 |
| 卷号 | 48期号:9页码:2496-2502 |
| 关键词 | Functionalization Of Polymers Polyolefins Friedel-crafts Acylation Reaction |
| ISSN号 | 0032-3861 |
| DOI | 10.1016/j.polymer.2007.02.036 |
| 英文摘要 | The strong polar group, carboxylic acid, has triumphantly been introduced into ethylene and allylbenzene copolymers without obvious degradation or crosslinking via Friedel-Crafts (F-C) acylation reaction with glutaric anhydride (GA), succinic anhydride (SA) and phthalic anhydride (PA) in the presence of anhydrous aluminum chloride in carbon disulfide. Some important reaction parameters were examined in order to optimize the acylation process. In the optimum reaction conditions, almost all of the phenyls can be acylated with any anhydride. The microstructure of acylated copolymer was characterized by Fr-IR, H-1 NMR and H-1-H-1 COSY. All the peaks of acylated copolymers can be accurately attributed, which indicates that all the acylation reactions occur only at the para-positions of the substituent of the aromatic rings. The thermal behavior was studied by differential scanning calorimetry (DSC), showing that the melting temperatures (T(m)s) of acylated copolymers with GA firstly decrease slowly and then increase significantly with the increase of the amount of carboxyl acid groups. (c) 2007 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000246329300007 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/62459]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Yuesheng |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, Yi,Li, Yanguo,Pan, Li,et al. Synthesis of novel functional polyolefin containing carboxylic acid via Friedel-Crafts acylation reaction[J]. POLYMER,2007,48(9):2496-2502. |
| APA | Zheng, Yi,Li, Yanguo,Pan, Li,&Li, Yuesheng.(2007).Synthesis of novel functional polyolefin containing carboxylic acid via Friedel-Crafts acylation reaction.POLYMER,48(9),2496-2502. |
| MLA | Zheng, Yi,et al."Synthesis of novel functional polyolefin containing carboxylic acid via Friedel-Crafts acylation reaction".POLYMER 48.9(2007):2496-2502. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。