Promoting effect of oxometallic acids, heteropoly acids of Mo, W and their salts on rhodium catalyzed methanol carbonylation
文献类型：期刊论文
| 作者 | Qian, Qingli; Zhang, Shufeng; Yuan, Guoqing |
| 刊名 | CATALYSIS COMMUNICATIONS
 |
| 出版日期 | 2007-03-01 |
| 卷号 | 8期号:3页码:483-487 |
| 关键词 | Methanol Carbonylation Oxometallic Acids Heteropoly Acids Rhodium Catalyst Catalytic Activity |
| ISSN号 | 1566-7367 |
| DOI | 10.1016/j.catcom.2006.07.025 |
| 英文摘要 | Oxometallic acids, heteropoly acids (HPAs) of Mo, W and their sodium salts were investigated as promoters for homogeneous rhodium catalyzed methanol carbonylation. The experiments were carried out under low water conditions. All of the catalysts with the promoters demonstrate better catalytic activity than the pristine Monsanto catalyst. And the promoting effects of acids upon reaction rates are generally better than the salts. The catalysts with the salts of HPAs as promoters have the best stability in the reactions. The catalytic rate can be effectively enhanced by increasing the content of the promoters, especially at low content level. (c) 2006 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000243163000052 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/62497]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yuan, Guoqing |
| 作者单位 | 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Lab New Mat, Inst Chem, Beijing 100080, Peoples R China 2.Tianjin Normal Univ, Coll Chem & Life Sci, Tianjin 300074, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qian, Qingli,Zhang, Shufeng,Yuan, Guoqing. Promoting effect of oxometallic acids, heteropoly acids of Mo, W and their salts on rhodium catalyzed methanol carbonylation[J]. CATALYSIS COMMUNICATIONS,2007,8(3):483-487. |
| APA | Qian, Qingli,Zhang, Shufeng,&Yuan, Guoqing.(2007).Promoting effect of oxometallic acids, heteropoly acids of Mo, W and their salts on rhodium catalyzed methanol carbonylation.CATALYSIS COMMUNICATIONS,8(3),483-487. |
| MLA | Qian, Qingli,et al."Promoting effect of oxometallic acids, heteropoly acids of Mo, W and their salts on rhodium catalyzed methanol carbonylation".CATALYSIS COMMUNICATIONS 8.3(2007):483-487. |
入库方式： OAI收割
来源：化学研究所
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