Anisotropic thermochemical hole burning phenomenon on TTF-TCNQ single crystal
文献类型：期刊论文
| 作者 | Ran, Chunbo; Peng, Hailin; Ren, Liang; Zhou, Wei; Ling, Yading; Liu, Zhongfan |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY C
 |
| 出版日期 | 2007-01-18 |
| 卷号 | 111期号:2页码:631-635 |
| ISSN号 | 1932-7447 |
| DOI | 10.1021/jp0650836 |
| 英文摘要 | A remarkable anisotropic thermochemical hole burning (THB) phenomenon was observed on TTF-TCNQ charge-transfer complex when using a STM tip to write information bits on its single-crystal surface. Such an anisotropy of hole formation was found to be closely related to the anisotropic thermal conducting property of TTF-TCNQ crystal, strongly supporting a nanometer scale thermochemical reaction mechanism. The high thermal conductivity of TTF-TCNQ leads to a very weak dependence of hole size on the pulse duration within a certain time scale, which was never observed with ammonium-TCNQ complexes. Comparative studies using isotropic thermal conducting TEA(TCNQ)2 complex and theoretical analyses were performed for elucidating the unique hole burning properties of TTF-TCNQ complex. The thermal gravimetry combined with mass spectrometry (TG-MS) of TTF-TCNQ was also done for a detailed understanding of the thermochernical decomposition reaction. |
| 语种 | 英语 |
| WOS记录号 | WOS:000245005300022 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/62577]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, Zhongfan |
| 作者单位 | Peking Univ, CNST, Beijing Natl Lab Mol Sci,Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ran, Chunbo,Peng, Hailin,Ren, Liang,et al. Anisotropic thermochemical hole burning phenomenon on TTF-TCNQ single crystal[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2007,111(2):631-635. |
| APA | Ran, Chunbo,Peng, Hailin,Ren, Liang,Zhou, Wei,Ling, Yading,&Liu, Zhongfan.(2007).Anisotropic thermochemical hole burning phenomenon on TTF-TCNQ single crystal.JOURNAL OF PHYSICAL CHEMISTRY C,111(2),631-635. |
| MLA | Ran, Chunbo,et al."Anisotropic thermochemical hole burning phenomenon on TTF-TCNQ single crystal".JOURNAL OF PHYSICAL CHEMISTRY C 111.2(2007):631-635. |
入库方式： OAI收割
来源：化学研究所
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