Highly oriented tunable wrinkling in polymer bilayer films confined with a soft mold induced by water vapor
文献类型:期刊论文
作者 | Qian, Weixian; Xing, Rubo; Yu, Xinhong; Quan, Xinjun; Han, Yanchun |
刊名 | JOURNAL OF CHEMICAL PHYSICS
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出版日期 | 2007-02-14 |
卷号 | 126期号:6 |
ISSN号 | 0021-9606 |
DOI | 10.1063/1.241647 |
英文摘要 | The authors report the formation of highly oriented wrinkling on the surface of the bilayer [polystyrene (PS)/poly(vinyl pyrrolidone) (PVP)] confined by a polydimethylsiloxane (PDMS) mold in a water vapor environment. When PVP is subjected to water vapor, the polymer loses its mechanical rigidity and changes to a viscous state, which leads to a dramatic change in Young's modulus. This change generates the amount of strain in the bilayer to induce the wrinkling. With a shape-controlled mold, they can get the ordered wrinkles perfectly perpendicular or leaned 45 S to the channel orientation of the mold because the orientation of the resultant force changes with the process of water diffusion which drives the surface to form the wrinkling. Additionally, they can get much smaller wrinkles than the stripe spacing of PDMS mold about one order. The wrinkle period changes with the power index of about 0.5 for various values of the multiplication product of the film thicknesses of the two layers, namely, lambda similar to (h(PS)h(PVP))(1/2). (c) 2007 American Institute of Physics. |
语种 | 英语 |
WOS记录号 | WOS:000244250200034 |
出版者 | AMER INST PHYSICS |
源URL | [http://ir.iccas.ac.cn/handle/121111/62671] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Qian, Weixian |
作者单位 | 1.Jilin Univ, Coll Chem, Changchun 130012, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 3.Jilin Univ, Coll Chem, Changchun 130012, Peoples R China |
推荐引用方式 GB/T 7714 | Qian, Weixian,Xing, Rubo,Yu, Xinhong,et al. Highly oriented tunable wrinkling in polymer bilayer films confined with a soft mold induced by water vapor[J]. JOURNAL OF CHEMICAL PHYSICS,2007,126(6). |
APA | Qian, Weixian,Xing, Rubo,Yu, Xinhong,Quan, Xinjun,&Han, Yanchun.(2007).Highly oriented tunable wrinkling in polymer bilayer films confined with a soft mold induced by water vapor.JOURNAL OF CHEMICAL PHYSICS,126(6). |
MLA | Qian, Weixian,et al."Highly oriented tunable wrinkling in polymer bilayer films confined with a soft mold induced by water vapor".JOURNAL OF CHEMICAL PHYSICS 126.6(2007). |
入库方式: OAI收割
来源:化学研究所
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