A hybrid organic-inorganic conductor kappa '-BETS2FeCl4, BETS = bis(ethylenedithio)tetraselenafulvalene
文献类型：期刊论文
| 作者 | Zhang, Bin; Pratt, Francis Laurence; Kurmoo, Mohamedally; Okano, Yoshinori; Kobayashi, Hayao; Zhu, Daoben |
| 刊名 | CRYSTAL GROWTH & DESIGN
 |
| 出版日期 | 2007-12-01 |
| 卷号 | 7期号:12页码:2548-2552 |
| ISSN号 | 1528-7483 |
| DOI | 10.1021/cg0704605 |
| 英文摘要 | A hybrid organic-inorganic conductor kappa'-BETS2FeCl4 is obtained by an electrocrystallization method from BETS and (Me4N)(3)Fe(C2O4)(3) dissolved in a mixture of C6H5Cl and C2H5OH under 2.0 V for 4 weeks. It belongs to the monoclinic space group C2/c, with cell parameters a = 37.783(9), b = 11.207(3), c = 8.530(2) angstrom, beta = 94.835(1)degrees, V = 3598.8(1.4) angstrom(3), and Z = 4. The donor arrangement resembles the kappa-phase but is different to that of the previously reported antiferromagnetic superconductor kappa-BETS2FeCl4, which is orthorhombic and has been studied for 10 years. The inorganic anion exists in two opposite configurations in the anion sheet Of kappa'-BETS2FeCl4, and its crystal structure and electronic structure are different from those of the polymorphs lambda-BETS2FeCl4 and kappa-BETS2FeCl4. |
| 语种 | 英语 |
| WOS记录号 | WOS:000251473200033 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/62681]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, Bin |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 2.Rutherford Appleton Lab, ISIS, Didcot OX11 0QX, Oxon, England 3.Univ Strasbourg 1, Inst Le Bel, Tecton Mol Solide, UMR7140,Lab Chim Coordinat Organ, F-67000 Strasbourg, France 4.Inst Mol Sci, Okazaki, Aichi 444, Japan |
| 推荐引用方式 GB/T 7714 | Zhang, Bin,Pratt, Francis Laurence,Kurmoo, Mohamedally,et al. A hybrid organic-inorganic conductor kappa '-BETS2FeCl4, BETS = bis(ethylenedithio)tetraselenafulvalene[J]. CRYSTAL GROWTH & DESIGN,2007,7(12):2548-2552. |
| APA | Zhang, Bin,Pratt, Francis Laurence,Kurmoo, Mohamedally,Okano, Yoshinori,Kobayashi, Hayao,&Zhu, Daoben.(2007).A hybrid organic-inorganic conductor kappa '-BETS2FeCl4, BETS = bis(ethylenedithio)tetraselenafulvalene.CRYSTAL GROWTH & DESIGN,7(12),2548-2552. |
| MLA | Zhang, Bin,et al."A hybrid organic-inorganic conductor kappa '-BETS2FeCl4, BETS = bis(ethylenedithio)tetraselenafulvalene".CRYSTAL GROWTH & DESIGN 7.12(2007):2548-2552. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。