中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A hybrid organic-inorganic conductor kappa '-BETS2FeCl4, BETS = bis(ethylenedithio)tetraselenafulvalene

文献类型:期刊论文

作者Zhang, Bin; Pratt, Francis Laurence; Kurmoo, Mohamedally; Okano, Yoshinori; Kobayashi, Hayao; Zhu, Daoben
刊名CRYSTAL GROWTH & DESIGN
出版日期2007-12-01
卷号7期号:12页码:2548-2552
ISSN号1528-7483
DOI10.1021/cg0704605
英文摘要A hybrid organic-inorganic conductor kappa'-BETS2FeCl4 is obtained by an electrocrystallization method from BETS and (Me4N)(3)Fe(C2O4)(3) dissolved in a mixture of C6H5Cl and C2H5OH under 2.0 V for 4 weeks. It belongs to the monoclinic space group C2/c, with cell parameters a = 37.783(9), b = 11.207(3), c = 8.530(2) angstrom, beta = 94.835(1)degrees, V = 3598.8(1.4) angstrom(3), and Z = 4. The donor arrangement resembles the kappa-phase but is different to that of the previously reported antiferromagnetic superconductor kappa-BETS2FeCl4, which is orthorhombic and has been studied for 10 years. The inorganic anion exists in two opposite configurations in the anion sheet Of kappa'-BETS2FeCl4, and its crystal structure and electronic structure are different from those of the polymorphs lambda-BETS2FeCl4 and kappa-BETS2FeCl4.
语种英语
WOS记录号WOS:000251473200033
出版者AMER CHEMICAL SOC
源URL[http://ir.iccas.ac.cn/handle/121111/62681]  
专题中国科学院化学研究所
通讯作者Zhang, Bin
作者单位1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
2.Rutherford Appleton Lab, ISIS, Didcot OX11 0QX, Oxon, England
3.Univ Strasbourg 1, Inst Le Bel, Tecton Mol Solide, UMR7140,Lab Chim Coordinat Organ, F-67000 Strasbourg, France
4.Inst Mol Sci, Okazaki, Aichi 444, Japan
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GB/T 7714
Zhang, Bin,Pratt, Francis Laurence,Kurmoo, Mohamedally,et al. A hybrid organic-inorganic conductor kappa '-BETS2FeCl4, BETS = bis(ethylenedithio)tetraselenafulvalene[J]. CRYSTAL GROWTH & DESIGN,2007,7(12):2548-2552.
APA Zhang, Bin,Pratt, Francis Laurence,Kurmoo, Mohamedally,Okano, Yoshinori,Kobayashi, Hayao,&Zhu, Daoben.(2007).A hybrid organic-inorganic conductor kappa '-BETS2FeCl4, BETS = bis(ethylenedithio)tetraselenafulvalene.CRYSTAL GROWTH & DESIGN,7(12),2548-2552.
MLA Zhang, Bin,et al."A hybrid organic-inorganic conductor kappa '-BETS2FeCl4, BETS = bis(ethylenedithio)tetraselenafulvalene".CRYSTAL GROWTH & DESIGN 7.12(2007):2548-2552.

入库方式: OAI收割

来源:化学研究所

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