Crystal engineering based on polymeric hydrogen-bonded supramolecules by self-assembling of 9,10-bis(3,5-dihydroxyphenyl)anthracene and 2,2 ',4,4 '-Tetrahydroxybenzophenone with bipyridines
文献类型:期刊论文
作者 | Li, Xiaokang; Zhen, Lvyin; Fan, Yulan; Fan, Xiaolin; Zeng, Qingdao |
刊名 | INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
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出版日期 | 2007-03-01 |
卷号 | 8期号:3页码:241-258 |
关键词 | Crystal Engineering Crystal Structures Polymeric Supramolecular Structurer Hydrogen-bonding |
ISSN号 | 1422-0067 |
英文摘要 | 9,10-bis(3,5-dihydroxyphenyl) anthracene (BDHA) and 2,2',4,4'-tetrahydroxybenzophenone (THB) are crystallized with bipyridine bases 4,4'-bipyridyl (bipy), 1,2-bis(4-pyridyl) ethane (bipy-eta), 1,2-di(4-pyridyl) ethylene (dipy-ete), 1,3-di(4-pyridyl) propane (dipy-pra), 4,4'-dipyridyl sulfide (dipy-sul), and 4,4'-dipyridyl disulfide (dipy-dis) to afford molecular complexes (BDHA)center dot(bipy)(2) 1, (BDHA)center dot(bipy-eta)(2) 2, (BDHA)(0.5)center dot(dipy-pra)center dot CH3CH2OH 3, (BDHA)(0.5)center dot(dipy-sul)center dot H2O 4, (BDHA)(0.5)center dot(dipy-dis) center dot CH3CH2OH 5 and (THB)center dot(dipy-ete)(2)center dot H2O 6. The crystal structures of 1-6 have been determined by single-crystal X-ray diffraction. All these molecular complexes exhibit polymeric supramolecular structures via O-H center dot center dot center dot N or O-H center dot center dot center dot O hydrogen-bonding. 1 and 2 form infinitely rectangular macrocycles linked with one another, whose sizes are ca. 12.477 angstrom x 4.802 angstrom and ca. 14.575 angstrom x 4.809 angstrom, respectively. 3, 5 and 6 form the one-dimensional zigzag chain structure. 4 forms a ladder structure, and two dipy-sul molecules were included in a frame. |
语种 | 英语 |
WOS记录号 | WOS:000245396500006 |
出版者 | MDPI AG |
源URL | [http://ir.iccas.ac.cn/handle/121111/62695] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Fan, Xiaolin |
作者单位 | 1.Gannan Normal Univ, Key Lab Organopharmaceut Chem Jiangxi Prov, Ganzhou 341000, JiangXi, Peoples R China 2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Xiaokang,Zhen, Lvyin,Fan, Yulan,et al. Crystal engineering based on polymeric hydrogen-bonded supramolecules by self-assembling of 9,10-bis(3,5-dihydroxyphenyl)anthracene and 2,2 ',4,4 '-Tetrahydroxybenzophenone with bipyridines[J]. INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES,2007,8(3):241-258. |
APA | Li, Xiaokang,Zhen, Lvyin,Fan, Yulan,Fan, Xiaolin,&Zeng, Qingdao.(2007).Crystal engineering based on polymeric hydrogen-bonded supramolecules by self-assembling of 9,10-bis(3,5-dihydroxyphenyl)anthracene and 2,2 ',4,4 '-Tetrahydroxybenzophenone with bipyridines.INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES,8(3),241-258. |
MLA | Li, Xiaokang,et al."Crystal engineering based on polymeric hydrogen-bonded supramolecules by self-assembling of 9,10-bis(3,5-dihydroxyphenyl)anthracene and 2,2 ',4,4 '-Tetrahydroxybenzophenone with bipyridines".INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES 8.3(2007):241-258. |
入库方式: OAI收割
来源:化学研究所
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