A novel efficient route for preparation of chiral beta-hydroxycarboxylic acid: Asymmetric hydration of unsaturated carboxylic acids catalyzed by heterobimetallic complex wool-palladium-cobalt
文献类型：期刊论文
| 作者 | Wang, Si-Qian; Wang, Zi-Wei; Yang, Lin-Chun; Dong, Jin-Long; Chi, Cai-Qin; Sui, Dan-Ni; Wang, Yong-Zhao; Ren, Jian-Guo; Hung, Mei-Yu; Jiang, Ying-Yan |
| 刊名 | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
 |
| 出版日期 | 2007-03-01 |
| 卷号 | 264期号:1-2页码:60-65 |
| 关键词 | Chiral Beta-hydroxycarboxylic Acid Asymmetric Hydration Unsaturated Carboxylic Acids Heterobimetallic Complex Wool-palladium-cobalt |
| ISSN号 | 1381-1169 |
| DOI | 10.1016/j.molcata.2006.08.073 |
| 英文摘要 | A new bio-polymer heterobimetallic complex wool-Pd-Co is found to be a novel efficient catalyst for asymmetric hydration of unsaturated carboxylic acids with high enantioselectivity by simple and clean process under mild conditions. Chemical and optical yields are affected by some parameters, such as the (Pd + Co) content in wool-Pd-Co, the Co/Pd molar ratio, reaction time, reaction temperature and amount of water. After five-time use of the complex, the chemical and optical yields of the products show no significant changes. Obviously, the methods provide an alternative way to produce chiral beta-hydroxycarboxylic acids. (c) 2006 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000244838200011 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/62829]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ren, Jian-Guo |
| 作者单位 | 1.ShanXi Univ, Coll Chem & Chem Engn, Taiyuan 030006, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Si-Qian,Wang, Zi-Wei,Yang, Lin-Chun,et al. A novel efficient route for preparation of chiral beta-hydroxycarboxylic acid: Asymmetric hydration of unsaturated carboxylic acids catalyzed by heterobimetallic complex wool-palladium-cobalt[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2007,264(1-2):60-65. |
| APA | Wang, Si-Qian.,Wang, Zi-Wei.,Yang, Lin-Chun.,Dong, Jin-Long.,Chi, Cai-Qin.,...&Jiang, Ying-Yan.(2007).A novel efficient route for preparation of chiral beta-hydroxycarboxylic acid: Asymmetric hydration of unsaturated carboxylic acids catalyzed by heterobimetallic complex wool-palladium-cobalt.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,264(1-2),60-65. |
| MLA | Wang, Si-Qian,et al."A novel efficient route for preparation of chiral beta-hydroxycarboxylic acid: Asymmetric hydration of unsaturated carboxylic acids catalyzed by heterobimetallic complex wool-palladium-cobalt".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 264.1-2(2007):60-65. |
入库方式： OAI收割
来源：化学研究所
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