Electrochemistry of Sc3N@C-78 and Sc3N@C-80 (I-h): On achieving reversible redox waves of the trimetal nitride endohedral fullerenes
文献类型：期刊论文
| 作者 | Zhang, Lin; Chen, Ning; Fan, Louzhen; Wang, Chunru; Yang, Shihe |
| 刊名 | JOURNAL OF ELECTROANALYTICAL CHEMISTRY
 |
| 出版日期 | 2007-09-15 |
| 卷号 | 608期号:1页码:15-21 |
| 关键词 | Trimetal Nitride Endohedral Fullerenes Electrochemistry Reversibility Sc3n@c-78 Sc3n@c-80 |
| ISSN号 | 1572-6657 |
| DOI | 10.1016/j.jelechem.2007.04.015 |
| 英文摘要 | Electrochemical behavior Of Sc3N@C-78 Solution was investigated for the first time by cyclic voltammetry (CV) as well as differential pulse voltammetry (DPV). Reversible redox features Of Sc3N@C-78 were obtained in contrast to that of Dy3N@C-78, for which the corresponding redox waves were very recently found to be irreversible. Toluene/MeCN and four other solvents have been identified, wherewith reversible redox waves can also be observed for Sc3N@C-80 (I-n) at a normal potential scan rate, whereas o-dichlorobenzene (o-DCB) was found to give only irreversible redox behavior as concluded by other researchers. The redox properties Of Sc3N@C78 and Sc3N@C-80 (I-n) are comparatively discussed on the basis of their different electronic structures and interactions with the solvent molecules. Additionally, electrochemical energy gaps of both Sc3N@C78 and Sc3N@C-80 (I-n) were obtained. (c) 2007 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000250241200003 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/62849]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, Shihe |
| 作者单位 | 1.Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China 2.Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China 3.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Lin,Chen, Ning,Fan, Louzhen,et al. Electrochemistry of Sc3N@C-78 and Sc3N@C-80 (I-h): On achieving reversible redox waves of the trimetal nitride endohedral fullerenes[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY,2007,608(1):15-21. |
| APA | Zhang, Lin,Chen, Ning,Fan, Louzhen,Wang, Chunru,&Yang, Shihe.(2007).Electrochemistry of Sc3N@C-78 and Sc3N@C-80 (I-h): On achieving reversible redox waves of the trimetal nitride endohedral fullerenes.JOURNAL OF ELECTROANALYTICAL CHEMISTRY,608(1),15-21. |
| MLA | Zhang, Lin,et al."Electrochemistry of Sc3N@C-78 and Sc3N@C-80 (I-h): On achieving reversible redox waves of the trimetal nitride endohedral fullerenes".JOURNAL OF ELECTROANALYTICAL CHEMISTRY 608.1(2007):15-21. |
入库方式： OAI收割
来源：化学研究所
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