中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Dispersing multi-walled carbon nanotubes with water-soluble block copolymers and their use as supports for metal nanoparticles

文献类型:期刊论文

作者Wang, Zhimin; Liu, Qingchun; Zhu, Hui; Liu, Hanfan; Chen, Yongming; Yang, Mingshu
刊名CARBON
出版日期2007-02-01
卷号45期号:2页码:285-292
ISSN号0008-6223
DOI10.1016/j.carbon.2006.09.025
英文摘要Oxidized multi-walled carbon nanotubes (MWCNTs) were dispersed in aqueous and organic solvents by non-covalent modification with a double-hydrophilic block copolymer, poly(ethylene oxide)-b-poly [2-(N,N-dimethylamino)ethy1 methacrylate] (PEO-b-PDMA). The PDMA segments were anchored onto the surface of the oxidized MWCNTs through multi-site zwitterionic interactions between the amino and the carboxyl groups while the PEO segments formed corona to promote the solubility of MWCNTs in different solvents. FT-IR and H-1 NMR spectroscopy gave structural information on the resulting composite, supporting the successful modification. Thermal gravimetric analysis showed that the grafting yield could reach 26%. UV/vis and transmission electron microscopy provided direct evidence for the individual dispersion. The resulting modified MWCNTs could find broad spectrum of applications. As an example, An and Pt nanoparticles were attached on the sidewall of the modified MWCNTs by using the amino groups of PDMA segments. (c) 2006 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000244270600009
出版者PERGAMON-ELSEVIER SCIENCE LTD
源URL[http://ir.iccas.ac.cn/handle/121111/62931]  
专题中国科学院化学研究所
通讯作者Chen, Yongming
作者单位1.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Joint Lab Polymer Sci & Mat, Inst Chem, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Wang, Zhimin,Liu, Qingchun,Zhu, Hui,et al. Dispersing multi-walled carbon nanotubes with water-soluble block copolymers and their use as supports for metal nanoparticles[J]. CARBON,2007,45(2):285-292.
APA Wang, Zhimin,Liu, Qingchun,Zhu, Hui,Liu, Hanfan,Chen, Yongming,&Yang, Mingshu.(2007).Dispersing multi-walled carbon nanotubes with water-soluble block copolymers and their use as supports for metal nanoparticles.CARBON,45(2),285-292.
MLA Wang, Zhimin,et al."Dispersing multi-walled carbon nanotubes with water-soluble block copolymers and their use as supports for metal nanoparticles".CARBON 45.2(2007):285-292.

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来源:化学研究所

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