Photocatalytic degradation of dimethyl phthalate ester using novel hydrophobic TiO2 pillared montmorillonite photocatalyst
文献类型：期刊论文
| 作者 | Ding, Xuejun1,2; An, Taicheng1; Li, Guiying1; Chen, Jiaxin1,2; Sheng, Guoying1; Fu, Jiamo1; Zhao, Jincai3 |
| 刊名 | RESEARCH ON CHEMICAL INTERMEDIATES
 |
| 出版日期 | 2008 |
| 卷号 | 34期号:1页码:67-83 |
| 关键词 | Pillared Clay Synthesis Dimethyl Phthalate Ester Adsorption Photocatalysis Degradation Pathways |
| ISSN号 | 0922-6168 |
| 英文摘要 | TiO2 pillared montmorillonites were prepared by introducing Ti4+ into a layer of montmorillonite modified with or without cetyltrimethylammonium bromide. The components and texture of the prepared composites were characterized by thermogravimetric analysis, X-ray powder diffraction and scanning electron microscopy. The adsorption and photocatalytic degradation performance of a model environmental endocrine disruptor, dimethyl phthalate ester, were investigated using this newly prepared hydrophobic TiO2 pillared montmorillonite photocatalyst. The adsorption of dimethyl phthalate ester from water varied from 9% to 28% on the prepared hydrophobic photocatalyst. Although the experimental results showed that the photocatalytic activity of the hydrophobic photocatalyst was slightly lower than that of hydrophilic one, electron spin resonance verified that hydroxyl radicals were also generated in hydrophobic TiO2 pillared montmorillonite photocatalyst under UV irradiation. To elucidate the decomposition mechanism of dimethyl phthalate ester, 12 main photocatalytic intermediates were identified during the photocatalytic degradation process, and a plausible degradation mechanism was also proposed. |
| 语种 | 英语 |
| WOS记录号 | WOS:000253431600006 |
| 出版者 | SPRINGER |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/63011]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | An, Taicheng |
| 作者单位 | 1.Chinese Acad Sci, Guangzho Inst Geochem, Guangdong Key Lab Environm Resources Utilizat & P, State Key Lab Organ Geochem, Guangzhou 510640, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Ctr Mol Sci, Inst Chem, Lab Photochem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ding, Xuejun,An, Taicheng,Li, Guiying,et al. Photocatalytic degradation of dimethyl phthalate ester using novel hydrophobic TiO2 pillared montmorillonite photocatalyst[J]. RESEARCH ON CHEMICAL INTERMEDIATES,2008,34(1):67-83. |
| APA | Ding, Xuejun.,An, Taicheng.,Li, Guiying.,Chen, Jiaxin.,Sheng, Guoying.,...&Zhao, Jincai.(2008).Photocatalytic degradation of dimethyl phthalate ester using novel hydrophobic TiO2 pillared montmorillonite photocatalyst.RESEARCH ON CHEMICAL INTERMEDIATES,34(1),67-83. |
| MLA | Ding, Xuejun,et al."Photocatalytic degradation of dimethyl phthalate ester using novel hydrophobic TiO2 pillared montmorillonite photocatalyst".RESEARCH ON CHEMICAL INTERMEDIATES 34.1(2008):67-83. |
入库方式： OAI收割
来源：化学研究所
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