A study on the double melting behavior of poly(trimethylene terephthalate)
文献类型：期刊论文
| 作者 | Zeng Wei1,2; Li Huihui1,2; Liu TianXi3; Yan ShouKe1,2 |
| 刊名 | CHINESE SCIENCE BULLETIN
 |
| 出版日期 | 2008-07-01 |
| 卷号 | 53期号:14页码:2145-2155 |
| 关键词 | Poly(Trimethylene Terephthalate) Double Melting Behavior Primary And Secondary Crystallization |
| ISSN号 | 1001-6538 |
| DOI | 10.1007/s11434-008-0301-x |
| 英文摘要 | Double melting behavior of poly(trimethylene terephthalate) (PTT) was studied in detail by means of differential scanning calorimetry (DSC) and optical microscopy. The results indicate that the low-temperature melting peak of PTT at ca. 218 degrees C for the samples crystallized isothermally at 203 degrees C is associated with the melting of crystals produced by secondary crystallization, while the high-temperature melting peak of it at about 227 degrees C is related to the melting of the crystals produced by primary crystallization. The results further demonstrate that the PTT crystals growing non-isothermally during cooling process are thermodynamically unstable and can undergo structure reorganization during the DSC heating scan. The reorganized crystals melt at temperature higher than the crystals produced by secondary crystallization at 203 degrees C. Consequently, for the non-fully crystallized samples, the crystals grown during cooling also exhibit contribution to the high-temperature melting peak. |
| 语种 | 英语 |
| WOS记录号 | WOS:000258145100007 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/63043]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yan ShouKe |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China 3.Fudan Univ, Dept Macromol Sci, Shanghai 200230, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zeng Wei,Li Huihui,Liu TianXi,et al. A study on the double melting behavior of poly(trimethylene terephthalate)[J]. CHINESE SCIENCE BULLETIN,2008,53(14):2145-2155. |
| APA | Zeng Wei,Li Huihui,Liu TianXi,&Yan ShouKe.(2008).A study on the double melting behavior of poly(trimethylene terephthalate).CHINESE SCIENCE BULLETIN,53(14),2145-2155. |
| MLA | Zeng Wei,et al."A study on the double melting behavior of poly(trimethylene terephthalate)".CHINESE SCIENCE BULLETIN 53.14(2008):2145-2155. |
入库方式： OAI收割
来源：化学研究所
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