中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
pH-Regulated Molecular Self-Assemblies in a Cationic-Anionic Surfactant System: From a "1-2" Surfactant Pair to a "1-1" Surfactant Pair

文献类型:期刊论文

作者Lin, Yiyang1; Han, Xue1; Cheng, Xinhao1; Huang, Jianbin1; Liang, Dehai2; Yu, Cailan3
刊名LANGMUIR
出版日期2008-12-16
卷号24期号:24页码:13918-13924
ISSN号0743-7463
DOI10.1021/la802593n
英文摘要With the aid of pH variation, direct transformation of a "1-1" cationic-anionic surfactant pair to a "1-2" cationic-anionic surfactant pair was attained in the system of cetyltrimethylammonium bromide and n-decylphosphoric acid. Owing to the transformation of a "1-1" pair to a "1-2" pair, diverse microstructures and peculiar phase behavior in this cationic-anionic surfactant mixture was obtained at different pH. It is proposed that pH can be manipulated for effectively tailoring the self-assembled organization in this cationic-anionic surfactant system, including spherical micelle, wormlike micelle, vesicle, and lamellar structure. In contrast to the conventional "1-1" surfactant pair, the "1-2" cationic-anionic surfactant pair exhibits unexpectedly weak aggregating ability. It is suggested that the hydrated volume of surfactant headaroup should be taken into consideration to better elucidate the self-assembly behavior of these "1-2" cationic-anionic surfactant mixtures.
语种英语
WOS记录号WOS:000261631700019
出版者AMER CHEMICAL SOC
源URL[http://ir.iccas.ac.cn/handle/121111/63063]  
专题中国科学院化学研究所
通讯作者Huang, Jianbin
作者单位1.Peking Univ, BNLMS, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100871, Peoples R China
2.Peking Univ, Key Lab Polymer Chem & Phys, Minist Educ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
3.Chinese Acad Sci, Inst Chem, CAS Key Lab Photochem, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Lin, Yiyang,Han, Xue,Cheng, Xinhao,et al. pH-Regulated Molecular Self-Assemblies in a Cationic-Anionic Surfactant System: From a "1-2" Surfactant Pair to a "1-1" Surfactant Pair[J]. LANGMUIR,2008,24(24):13918-13924.
APA Lin, Yiyang,Han, Xue,Cheng, Xinhao,Huang, Jianbin,Liang, Dehai,&Yu, Cailan.(2008).pH-Regulated Molecular Self-Assemblies in a Cationic-Anionic Surfactant System: From a "1-2" Surfactant Pair to a "1-1" Surfactant Pair.LANGMUIR,24(24),13918-13924.
MLA Lin, Yiyang,et al."pH-Regulated Molecular Self-Assemblies in a Cationic-Anionic Surfactant System: From a "1-2" Surfactant Pair to a "1-1" Surfactant Pair".LANGMUIR 24.24(2008):13918-13924.

入库方式: OAI收割

来源:化学研究所

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