Two magnetic metal coordination polymers with tetrazolyl ligands through in situ reactions
文献类型：期刊论文
| 作者 | Li Ru-Yin; Gao Song |
| 刊名 | CHINESE JOURNAL OF INORGANIC CHEMISTRY
 |
| 出版日期 | 2008-08-10 |
| 卷号 | 24期号:8页码:1229-1236 |
| ISSN号 | 1001-4861 |
| 关键词 | Tetrazole Azide Cobalt Manganese Structure Magnetism |
| 英文摘要 | The Demko-Sharpless' is a very effective method for synthesis of the tetrazole compounds. Using this method, two coordination polymers have been obtained using solvent thermal reactions, and characterized structurally and magnetically. The 2D layer 1, CO3(3-ptz)(4)(N-3)(2)(H2O)(2)center dot 4H(2)O is consisted of 1D azido-bridged Co2+ chains linked through the coordinated Co2+ building block. The 3D network 2, Mn-3(3-ptz)(2)(N-3)(4)(H2O)center dot 0.5H(2)O is consisted with complicated 2D azido-bridged Mn2+ layers pillared by bridge ligands. The excessive azide ions in the reaction adopt mu-1, 1, mu-1,3 modes in 1 and mu-1, 1, mu-1,3, mu-1,1,3 modes in 2, bridge the neighboring metal ions and transmit magnetic couplings. The 3-(pyridinyl)tetrazole anion, which is the production of the Demko-Sharpless' reaction, bridges with bidentate and tridentate mode in 1, with tridentate and pentadentate mode in 2. They not. only bridge the metal Ions, but also transmit magnetic couplings along with azide ions. CCDC: 687279, 1; 687279, 2. |
| 语种 | 英语 |
| 出版者 | CHINESE CHEMICAL SOC |
| WOS记录号 | WOS:000258639900007 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/63071]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Gao Song |
| 作者单位 | Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li Ru-Yin,Gao Song. Two magnetic metal coordination polymers with tetrazolyl ligands through in situ reactions[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2008,24(8):1229-1236. |
| APA | Li Ru-Yin,&Gao Song.(2008).Two magnetic metal coordination polymers with tetrazolyl ligands through in situ reactions.CHINESE JOURNAL OF INORGANIC CHEMISTRY,24(8),1229-1236. |
| MLA | Li Ru-Yin,et al."Two magnetic metal coordination polymers with tetrazolyl ligands through in situ reactions".CHINESE JOURNAL OF INORGANIC CHEMISTRY 24.8(2008):1229-1236. |
入库方式： OAI收割
来源：化学研究所
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