An aluminoborate cluster [AlB(12)O(14)(OH)(12)]: synthesis and structure of [C(5)H(6)N][AlB(12)O(14)(OH)(12)]
文献类型：期刊论文
| 作者 | Yang, Sihai; Li, Guobao; Ju, Jing; Yang, Ziliang; Liao, Fuhui; Wang, Yingxia; Lin, Jianhua |
| 刊名 | INORGANICA CHIMICA ACTA
 |
| 出版日期 | 2008-06-02 |
| 卷号 | 361期号:8页码:2413-2417 |
| 关键词 | Polyborate Aluminoborate Hydrothermal Reaction Cluster Supramolecular |
| ISSN号 | 0020-1693 |
| DOI | 10.1016/j.ica.2007.12.025 |
| 英文摘要 | A new aluminoborate, [C(5)H(6)N][AlB(12)O(14)(OH)(12)], has been hydrothermally synthesized at 200 degrees C. The single-crystal diffraction study reveals that it crystallizes in space group C2/c. It consists of aluminoborate clusters [AlB(12)O(14)(OH)(12)](-) and counterions [C(5)H(6)N](+). The aluminoborate cluster contains an Al(OH)(6) octahedron as a core that is capped by two raft-like polyborate units [B(6)O(7)(OH)(6)]. These clusters are further interlinked by extensive hydrogen bonding to form a three-dimensional (3D) network, containing large channels along the b-axis, in which the [C(5)H(6)N](+) cations are located. (C) 2007 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000256093600028 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/63087]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Guobao |
| 作者单位 | Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Sihai,Li, Guobao,Ju, Jing,et al. An aluminoborate cluster [AlB(12)O(14)(OH)(12)]: synthesis and structure of [C(5)H(6)N][AlB(12)O(14)(OH)(12)][J]. INORGANICA CHIMICA ACTA,2008,361(8):2413-2417. |
| APA | Yang, Sihai.,Li, Guobao.,Ju, Jing.,Yang, Ziliang.,Liao, Fuhui.,...&Lin, Jianhua.(2008).An aluminoborate cluster [AlB(12)O(14)(OH)(12)]: synthesis and structure of [C(5)H(6)N][AlB(12)O(14)(OH)(12)].INORGANICA CHIMICA ACTA,361(8),2413-2417. |
| MLA | Yang, Sihai,et al."An aluminoborate cluster [AlB(12)O(14)(OH)(12)]: synthesis and structure of [C(5)H(6)N][AlB(12)O(14)(OH)(12)]".INORGANICA CHIMICA ACTA 361.8(2008):2413-2417. |
入库方式： OAI收割
来源：化学研究所
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