Melt crystallization and crystal transition of poly(butylene adipate) revealed by infrared spectroscopy
文献类型：期刊论文
| 作者 | Yan, Chao2; Zhang, Ying2; Hu, Yun3; Ozaki, Yukihiro3; Shen, Deyan1; Gan, Zhihua1; Yan, Shouke1; Takahashi, Isao2 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY B
 |
| 出版日期 | 2008-03-20 |
| 卷号 | 112期号:11页码:3311-3314 |
| ISSN号 | 1520-6106 |
| DOI | 10.1021/jp077195i |
| 英文摘要 | The structure evolution of poly(butylene adipate) (PBA) during isothermal melt crystallization and phase transition processes is investigated by Fourier transform infrared spectroscopy (FTIR). Detailed IR spectra analysis and band assignment are performed to disclose the bands sensitive to the alpha-form, crystalline order of PBA. It is revealed from the in situ IR study that the functionalities within PBA chains alter simultaneously during the melt crystallization process. From the analysis of the spectral changes, it is found that band shifts take place during the phase transition process of PBA from its metastable beta-form crystal to the stable alpha-form. Notable band shifts in the 1300-1100 cm(-1) region indicate that the twist of polymer chains in the alpha-form is located in the C-O-C and C-O linkages. Moreover, the results elucidated that the different segments of molecular chains tune up their conformations synchronously during the beta to alpha crystal transition process of PBA. It is suggested that the beta alpha phase transition process proceeds randomly throughout the solid at a constant rate. |
| 语种 | 英语 |
| WOS记录号 | WOS:000253945900007 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/63129]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yan, Shouke |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Polymer Phys & Chem, Inst Chem, Beijing 100080, Peoples R China 2.Kwansei Gakuin Univ, Dept Phys, Sch Sci & Technol, Gakuen, Sanda 6691337, Japan 3.Kwansei Gakuin Univ, Dept Chem, Sch Sci & Technol, Gakuen, Sanda 6691337, Japan |
| 推荐引用方式 GB/T 7714 | Yan, Chao,Zhang, Ying,Hu, Yun,et al. Melt crystallization and crystal transition of poly(butylene adipate) revealed by infrared spectroscopy[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2008,112(11):3311-3314. |
| APA | Yan, Chao.,Zhang, Ying.,Hu, Yun.,Ozaki, Yukihiro.,Shen, Deyan.,...&Takahashi, Isao.(2008).Melt crystallization and crystal transition of poly(butylene adipate) revealed by infrared spectroscopy.JOURNAL OF PHYSICAL CHEMISTRY B,112(11),3311-3314. |
| MLA | Yan, Chao,et al."Melt crystallization and crystal transition of poly(butylene adipate) revealed by infrared spectroscopy".JOURNAL OF PHYSICAL CHEMISTRY B 112.11(2008):3311-3314. |
入库方式： OAI收割
来源：化学研究所
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