Palladium within ionic liquid functionalized mesoporous silica SBA-15 and its catalytic application in room-temperature Suzuki coupling reaction
文献类型：期刊论文
| 作者 | Han, Peng1,2; Zhang, Hongming2; Qiu, Xuepeng2; Ji, Xiangling1; Gao, Lianxun1,2 |
| 刊名 | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
 |
| 出版日期 | 2008-11-12 |
| 卷号 | 295期号:1-2页码:57-67 |
| 关键词 | Palladium Mesoporous Ionic Liquid Catalysis Coupling Suzuki Room Temperature |
| ISSN号 | 1381-1169 |
| DOI | 10.1016/j.molcata.2008.08.016 |
| 英文摘要 | Initially, pore walls of mesoporous silica SBA-15 with template were modified with chlorotrimethylsilane. Then imidazolium salts were similarly incorporated covalently in the inner pore walls of mesoporous silica SBA-15 albeit without the template. Finally, palladium salts were introduced into the pore channels of the previously processed mesoporous silica via electrostatic interaction. The resulting palladium catalysts demonstrated exceptional activity for the room-temperature Suzuki Coupling reaction in aqueous-organic mixed solvents and good recycling ability for at least 4-6 times. The turnover frequency Of resulting catalysts could reach tip to 84,000 h(-1) at 50 C. The corresponding samples were analyzed with solid-state NMR, FT-R, XRD, nitrogen adsorption-desorption isotherms, TEM and XPS techniques. In addition, agglomeration of palladium catalyst in the Suzuki coupling reaction can be effectively controlled due to the stabilizing effect of the imidazolium salt and confinement of mesoporous walls. (c) 2008 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000261275000010 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/63177]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ji, Xiangling |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Grad Sch, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, Lab Polymer Engn, Grad Sch, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Han, Peng,Zhang, Hongming,Qiu, Xuepeng,et al. Palladium within ionic liquid functionalized mesoporous silica SBA-15 and its catalytic application in room-temperature Suzuki coupling reaction[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2008,295(1-2):57-67. |
| APA | Han, Peng,Zhang, Hongming,Qiu, Xuepeng,Ji, Xiangling,&Gao, Lianxun.(2008).Palladium within ionic liquid functionalized mesoporous silica SBA-15 and its catalytic application in room-temperature Suzuki coupling reaction.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,295(1-2),57-67. |
| MLA | Han, Peng,et al."Palladium within ionic liquid functionalized mesoporous silica SBA-15 and its catalytic application in room-temperature Suzuki coupling reaction".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 295.1-2(2008):57-67. |
入库方式： OAI收割
来源：化学研究所
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