Synthesis and characterisation of novel functional polyolefin containing sulfonic acid groups
文献类型：期刊论文
| 作者 | Zheng, Yi1,2; Pan, Li1; Li, Yan-Guo1; Li, Yue-Sheng1 |
| 刊名 | EUROPEAN POLYMER JOURNAL
 |
| 出版日期 | 2008-02-01 |
| 卷号 | 44期号:2页码:475-482 |
| ISSN号 | 0014-3057 |
| 关键词 | Functionalization Of Polymers Polyolefins Sulfonation Reaction Polar Groups Hydrophilicity Chemical Modification |
| DOI | 10.1016/j.eurpolymj.2007.11.017 |
| 英文摘要 | The strong polar group, sulfonic acid, has successfully been introduced into ethylene/allylbenzene copolymers without degradation or crosslinking via chlorosulfonation reaction with chlorosulfonic acid as a chlorosulforiating agent in 1, 1,2,2-tetrachloroethane followed by hydrolysis. The degree of sulforiation (DS) can be easily controlled by changing the ratio of chlorosulfonic acid to the pendant phenyls of the copolymer. The microstructure of sulfonated copolymers were unambiguously revealed by H-1 NMR and H-1-H-1 COSY spectral analyses, which indicates that all the sulforiation reactions exclusively took place at the para-position of the aromatic rings. The thermal behaviors were studied by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). DSC data exhibit a systematic trend of melting temperature increasing with DS. TGA data of sulfonated copolymers show ail increase in degradation temperature from 444 to 460 degrees C compared to the received copolymer. Sulfonated copolymers also show an additional minor loss of mass at approximately 261 degrees C, which is not observed in the received copolymer. The wetting properties of the sulfonated copolymers were also evaluated by contact angle measurement, and a notable increase in surface hydrophilicity was identified. (c) 2007 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| WOS记录号 | WOS:000254116500021 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/63253]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Yue-Sheng |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, Yi,Pan, Li,Li, Yan-Guo,et al. Synthesis and characterisation of novel functional polyolefin containing sulfonic acid groups[J]. EUROPEAN POLYMER JOURNAL,2008,44(2):475-482. |
| APA | Zheng, Yi,Pan, Li,Li, Yan-Guo,&Li, Yue-Sheng.(2008).Synthesis and characterisation of novel functional polyolefin containing sulfonic acid groups.EUROPEAN POLYMER JOURNAL,44(2),475-482. |
| MLA | Zheng, Yi,et al."Synthesis and characterisation of novel functional polyolefin containing sulfonic acid groups".EUROPEAN POLYMER JOURNAL 44.2(2008):475-482. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。