中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Hole-transporting polymers containing carbazol-3,9-diyl and 1,4-phenylene fragments in the main chain

文献类型:期刊论文

作者Grigalevicius, Saulius1; Simokaitiene, Jurate1; Grazulevicius, Juozas V.1; Ma, Liang2; Xie, Zhiyuan2
刊名SYNTHETIC METALS
出版日期2008-11-01
卷号158期号:19-20页码:739-743
关键词Amorphous Material Copolymer Light Emitting Diode Thermal Stability
ISSN号0379-6779
DOI10.1016/j.synthmet.2008.04.025
英文摘要New carbazole-based polymers, which contain various content of electro-active fragments in the main chain connected via alkylene spacers, have been synthesized by Ni(0)-catalyzed Yamamoto-type aryl-aryl coupling reactions. These compounds represent amorphous materials of high thermal stability with glass-transition temperatures of 139-151 degrees C and thermal decomposition starting at temperatures above 400 degrees C. UV-vis absorption and photoluminescence emission spectra of the materials confirmed that the conjugated segments in the macromolecules are rather short. However, the polymers with varying content of the electro-active chromophores demonstrate different charge injection and transport properties in multilayer light emitting diodes with the polymers as the hole transport and tris(8-quinolinato)aluminium (Alq(3)) as the electroluminescent/electron transport layer. The device based on the polymer containing bicarbazole segments in the main chain exhibits the best overall performance (turn-on voltage: 4V; maximum photometric efficiency: 2.6cd/A; maximum brightness: approximately 2200cd/m(2)). (C) 2008 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000261361700001
出版者ELSEVIER SCIENCE SA
源URL[http://ir.iccas.ac.cn/handle/121111/63281]  
专题中国科学院化学研究所
通讯作者Grigalevicius, Saulius
作者单位1.Kaunas Univ Technol, Dept Organ Technol, LT-50254 Kaunas, Lithuania
2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
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GB/T 7714
Grigalevicius, Saulius,Simokaitiene, Jurate,Grazulevicius, Juozas V.,et al. Hole-transporting polymers containing carbazol-3,9-diyl and 1,4-phenylene fragments in the main chain[J]. SYNTHETIC METALS,2008,158(19-20):739-743.
APA Grigalevicius, Saulius,Simokaitiene, Jurate,Grazulevicius, Juozas V.,Ma, Liang,&Xie, Zhiyuan.(2008).Hole-transporting polymers containing carbazol-3,9-diyl and 1,4-phenylene fragments in the main chain.SYNTHETIC METALS,158(19-20),739-743.
MLA Grigalevicius, Saulius,et al."Hole-transporting polymers containing carbazol-3,9-diyl and 1,4-phenylene fragments in the main chain".SYNTHETIC METALS 158.19-20(2008):739-743.

入库方式: OAI收割

来源:化学研究所

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