Synthesis of acetic acid and acetic anhydride from methanol carbonylation with polymer supported rhodium catalyst
文献类型：期刊论文
| 作者 | Zhang, Shufeng2; Guo, Cunyue1; Qian, Qingh1; Yuan, Guoqing1 |
| 刊名 | CATALYSIS COMMUNICATIONS
 |
| 出版日期 | 2008-03-20 |
| 卷号 | 9期号:5页码:853-858 |
| 关键词 | Methanol Carbonylation Rhodium/polymer Catalyst Catalytic Activity |
| ISSN号 | 1566-7367 |
| DOI | 10.1016/j.catcom.2007.09.010 |
| 英文摘要 | Novel porous spherules fabricated via crosslinking copolymerization of 2-vinyl pyridine and ethylene glycol diacrylate and the subsequent formation of chelate complex with [Rh(CO)(2)Cl(2)](-) were reported in this paper. The complex is well swelled in the reaction medium. Advantages of this catalyst lied in the fact that it could rapidly catalyze carbonylation of methanol to acetic acid with high selectivity and directly formed some acetic anhydride under mild conditions ( >= 140 degrees C). In addition, occurrence of water gas shift reaction during the process is hardly observable. (c) 2007 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000253450900055 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/63339]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yuan, Guoqing |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Lab New Mat, Beijing 100080, Peoples R China 2.Tianjin Normal Univ, Coll Chem & Life Sci, Tianjin 300074, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Shufeng,Guo, Cunyue,Qian, Qingh,et al. Synthesis of acetic acid and acetic anhydride from methanol carbonylation with polymer supported rhodium catalyst[J]. CATALYSIS COMMUNICATIONS,2008,9(5):853-858. |
| APA | Zhang, Shufeng,Guo, Cunyue,Qian, Qingh,&Yuan, Guoqing.(2008).Synthesis of acetic acid and acetic anhydride from methanol carbonylation with polymer supported rhodium catalyst.CATALYSIS COMMUNICATIONS,9(5),853-858. |
| MLA | Zhang, Shufeng,et al."Synthesis of acetic acid and acetic anhydride from methanol carbonylation with polymer supported rhodium catalyst".CATALYSIS COMMUNICATIONS 9.5(2008):853-858. |
入库方式： OAI收割
来源：化学研究所
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