The photodimerization of a cinnamoyl moiety derivative in dilute solution based on the intramolecular chain interaction of gemini surfactant
文献类型：期刊论文
| 作者 | Fan, Haiming; Zhu, Xiaoming; Gao, Lining; Li, Zichen; Huang, Jianbin |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY B
 |
| 出版日期 | 2008-08-21 |
| 卷号 | 112期号:33页码:10165-10170 |
| ISSN号 | 1520-6106 |
| DOI | 10.1021/jp8017666 |
| 英文摘要 | A Gemini surfactant, sodium N,N'-di(4-n-butyloxy cinnamoly)-L-cystine, containing a cinnamoyl moiety in the alkyl chains and disulfide bond in the spacer was designed and synthesized. The incorporation of a cinnamoyl moiety into the alkyl chains of Gemini surfactant makes it easy to probe the conformational information of the amphiphile molecule. The UV/vis absorption spectra and steady-state fluorescence were investigated at a concentration far below the critical micelle concentration (cmc). Both blue-shift of absorption and red-shift of fluorescence emission spectra indicate the existence of intramolecular interaction between the two alkyl chains in Gemini surfactant in the singly dispersed state. Results based on the breakdown of the disulfide bond by dithiotheritol (DTT) further confirmed the conclusion. Moreover, the characteristic of intramolecular chain interaction in Gemini surfactant improves the topochemical geometrical requirements of cinnamoyl moiety and increases the local concentration of reactant in dilute solution. Utilizing the incorporation of cinnamoyl moiety into the alkyl chains of Gemini surfactant, the cinnamoyl moiety upon irradiation undergoes dimerization in dilute aqueous solution with high yield of 78%. |
| 语种 | 英语 |
| WOS记录号 | WOS:000258460400014 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/63361]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Huang, Jianbin |
| 作者单位 | Peking Univ, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fan, Haiming,Zhu, Xiaoming,Gao, Lining,et al. The photodimerization of a cinnamoyl moiety derivative in dilute solution based on the intramolecular chain interaction of gemini surfactant[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2008,112(33):10165-10170. |
| APA | Fan, Haiming,Zhu, Xiaoming,Gao, Lining,Li, Zichen,&Huang, Jianbin.(2008).The photodimerization of a cinnamoyl moiety derivative in dilute solution based on the intramolecular chain interaction of gemini surfactant.JOURNAL OF PHYSICAL CHEMISTRY B,112(33),10165-10170. |
| MLA | Fan, Haiming,et al."The photodimerization of a cinnamoyl moiety derivative in dilute solution based on the intramolecular chain interaction of gemini surfactant".JOURNAL OF PHYSICAL CHEMISTRY B 112.33(2008):10165-10170. |
入库方式： OAI收割
来源：化学研究所
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