Sulfonated poly(arylene-co-imide)s as water stable proton exchange membrane materials for fuel cells
文献类型：期刊论文
| 作者 | Li, Wenmu1,2; Cui, Zhiming2,3; Zhou, Xiaochun2,3; Zhang, Suobo1; Dai, Lei1; Xing, Wei3 |
| 刊名 | JOURNAL OF MEMBRANE SCIENCE
 |
| 出版日期 | 2008-05-01 |
| 卷号 | 315期号:1-2页码:172-179 |
| 关键词 | Sulfonated Copolyimides Water Stability Proton Exchange Membrane Proton Conductivity |
| ISSN号 | 0376-7388 |
| DOI | 10.1016/j.memsci.2008.02.026 |
| 英文摘要 | A novel sulfonated poly(arylene-co-imide)s were synthesized by Ni(0) catalytic copolymerization of sodium 3-(2,5-dichlorobenzoyl)benzenesulfonate and naphthalimide dichloride monomer. The synthesized copolymers with the - SO3H group on the side-chain of polymers possessed high molecular weights revealed by their high viscosity and the formation of tough and flexible membranes. Because of the introduction of electron donating phenoxy groups into naphthalimide moieties, the hydrolysis of the imide rings was depressed. The resulting copolymers exhibited excellent water stability. The copolymer membranes display no apparently change in appearance, flexibility, and toughness after a soaking treatment in pressurized water at 140 degrees C for 250 h. TEM analysis revealed that these side-chain type membranes have a microphase separated structure composed of hydrophilic side-chain domains and hydrophobic polyimide main chain domains. The proton conductivities of copolymer membranes increased with the increase of IEC and temperature, reaching values above 3.2 x 10(-1) S/cm at 80 degrees C, which are higher than Nafion 117 on the same measurement conditions. The methanol permeability of the copolymer membranes was one order lower than that of Nafion 117. Consequently, these Materials proved to be promising as Proton exchange membranes. (c) 2008 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000256104900021 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/63369]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Wenmu |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.State Key Lab Electroanalyt Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Wenmu,Cui, Zhiming,Zhou, Xiaochun,et al. Sulfonated poly(arylene-co-imide)s as water stable proton exchange membrane materials for fuel cells[J]. JOURNAL OF MEMBRANE SCIENCE,2008,315(1-2):172-179. |
| APA | Li, Wenmu,Cui, Zhiming,Zhou, Xiaochun,Zhang, Suobo,Dai, Lei,&Xing, Wei.(2008).Sulfonated poly(arylene-co-imide)s as water stable proton exchange membrane materials for fuel cells.JOURNAL OF MEMBRANE SCIENCE,315(1-2),172-179. |
| MLA | Li, Wenmu,et al."Sulfonated poly(arylene-co-imide)s as water stable proton exchange membrane materials for fuel cells".JOURNAL OF MEMBRANE SCIENCE 315.1-2(2008):172-179. |
入库方式： OAI收割
来源：化学研究所
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