Syntheses of opened hollow clay microspheres through a spray-drying approach and their derivative clay/carbon nanotubes composites
文献类型：期刊论文
| 作者 | Du, Xiaohua1,2; Jiang, Zhiwei1; Meng, Xiaoyu1,2; Wang, Zhe1,2; Yu, Haiou1,2; Li, Meiye1; Tang, Tao1 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY C
 |
| 出版日期 | 2008-05-01 |
| 卷号 | 112期号:17页码:6638-6642 |
| ISSN号 | 1932-7447 |
| DOI | 10.1021/jp712101f |
| 英文摘要 | Opened hollow microspheres of organoclays were prepared via spray drying the suspension of modified Na+-montmorillonite (Na+-MMT) with alkylsulfonate. The microstructure and thermal properties of these opened hollow spheres were characterized by means of wide-angle X-ray diffraction, field emission scanning electron microscopy, and thermogravimetric analysis. The results showed that the organoclays had larger interlayer spacing compared with pure Na+-MMT and higher thermal stability relative to the alkylsufonate. The reason for the formation of this novel structure was investigated. On the basis of the morphological investigation of the organoclays containing alkylsulfonate with different molecular length, the formation of the opened hollow microspheres was found to be related to the intercalation structure of the organoclays. The larger the interlayer distance of the organoclays was, the more the opened hollow microspheres were formed. Moreover, intercalating Co2+ ion within MMT galleries of the opened hollow microspheres via ion exchange could be applied to in situ synthesize clay/carbon nanotubes (clay/CNTs) composite by chemical vapor deposition after reduction. |
| 语种 | 英语 |
| WOS记录号 | WOS:000255292400008 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/63397]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Tang, Tao |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Du, Xiaohua,Jiang, Zhiwei,Meng, Xiaoyu,et al. Syntheses of opened hollow clay microspheres through a spray-drying approach and their derivative clay/carbon nanotubes composites[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2008,112(17):6638-6642. |
| APA | Du, Xiaohua.,Jiang, Zhiwei.,Meng, Xiaoyu.,Wang, Zhe.,Yu, Haiou.,...&Tang, Tao.(2008).Syntheses of opened hollow clay microspheres through a spray-drying approach and their derivative clay/carbon nanotubes composites.JOURNAL OF PHYSICAL CHEMISTRY C,112(17),6638-6642. |
| MLA | Du, Xiaohua,et al."Syntheses of opened hollow clay microspheres through a spray-drying approach and their derivative clay/carbon nanotubes composites".JOURNAL OF PHYSICAL CHEMISTRY C 112.17(2008):6638-6642. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。