Palladium nanoparticles in polyethylene glycols: Efficient and recyclable catalyst system for hydrogenation of olefins
文献类型：期刊论文
| 作者 | Ma, Xiumin; Jiang, Tao; Han, Buxing; Zhang, Jicheng; Mao, Shiding; Ding, Kunlun; An, Guimin; Xie, Ye; Zhou, Yinxi; Zhu, Anlian |
| 刊名 | CATALYSIS COMMUNICATIONS
 |
| 出版日期 | 2008 |
| 卷号 | 9期号:1页码:70-74 |
| 关键词 | Palladium Nanoparticles Catalysis Hydrogenation Olefins Pegs |
| ISSN号 | 1566-7367 |
| DOI | 10.1016/j.catcom.2007.05.028 |
| 英文摘要 | Hydrogenation of olefins catalyzed by palladium nanoparticles dispersed in polyethylene glycols (PEGs) was carried out. It was shown that Pd nanoparticles in PEG800 (PEG with an average molecular weight of 800 g/mol), PEG 1000, and PEG2000 were very active, stable, and selective for hydrogenation of a range of olefins at mild conditions. For simple alkenes like cyclohexene, the pure products were isolated by simple decantation because the miscibility of the products and the PEGs was extremely poor. For olefins with polar groups, the C=C double bonds were selectively hydrogenated with 100% selectivity. The reusability of Pd-PEG2000 was tested, and deactivation of the catalyst was not detectable after 10 recycles. (c) 2007 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000251573100014 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/63439]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jiang, Tao |
| 作者单位 | Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma, Xiumin,Jiang, Tao,Han, Buxing,et al. Palladium nanoparticles in polyethylene glycols: Efficient and recyclable catalyst system for hydrogenation of olefins[J]. CATALYSIS COMMUNICATIONS,2008,9(1):70-74. |
| APA | Ma, Xiumin.,Jiang, Tao.,Han, Buxing.,Zhang, Jicheng.,Mao, Shiding.,...&Zhu, Anlian.(2008).Palladium nanoparticles in polyethylene glycols: Efficient and recyclable catalyst system for hydrogenation of olefins.CATALYSIS COMMUNICATIONS,9(1),70-74. |
| MLA | Ma, Xiumin,et al."Palladium nanoparticles in polyethylene glycols: Efficient and recyclable catalyst system for hydrogenation of olefins".CATALYSIS COMMUNICATIONS 9.1(2008):70-74. |
入库方式： OAI收割
来源：化学研究所
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