Analysis of configurations of stable spin adducts of the O-2(-.) linear nitrones
文献类型：期刊论文
| 作者 | Ji Yi-Qiong; Wang Zhao-Yi; Wang Lan-Fen; Bao Peng; Liu Yang |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 2008-09-10 |
| 卷号 | 29期号:9页码:1801-1803 |
| 关键词 | Free Radical Spin Trap Superoxide Adduct Linear Nitrone Density Functional Theory (Dft) Electron-spin Resonance (Esr) |
| ISSN号 | 0251-0790 |
| 英文摘要 | Six linear nitrones, three DBN derivatives and their phosphoryl analogues, were first synthesized in this article, and the structures of their 0(2)(-.) -spin trapping products, the nitroxides, were theoretically and experimentally analyzed. The theoretical calculations on the optimized geometries of the spin adducts, using DFT method at B3LYP/6-311 + G (d,p)//B3LYP/6-31G (d) level, demonstrated that both the intromolecular H-bonds and their internal rotations around C-N bond are the key factors for stabilizing the spin adducts. |
| 语种 | 英语 |
| WOS记录号 | WOS:000259522800021 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/63447]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu Yang |
| 作者单位 | Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ji Yi-Qiong,Wang Zhao-Yi,Wang Lan-Fen,et al. Analysis of configurations of stable spin adducts of the O-2(-.) linear nitrones[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2008,29(9):1801-1803. |
| APA | Ji Yi-Qiong,Wang Zhao-Yi,Wang Lan-Fen,Bao Peng,&Liu Yang.(2008).Analysis of configurations of stable spin adducts of the O-2(-.) linear nitrones.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,29(9),1801-1803. |
| MLA | Ji Yi-Qiong,et al."Analysis of configurations of stable spin adducts of the O-2(-.) linear nitrones".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 29.9(2008):1801-1803. |
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来源：化学研究所
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