Photoinduced electron and energy transfer in dyads of porphyrin dimer and perylene tetracarboxylic diimide
文献类型:期刊论文
作者 | Xu, Wei1; Chen, Hailong3; Wang, Yanfeng; Zhao, Chuntao1; Li, Xiyou1; Wang, Shuangqing2; Weng, Yuxiang1,3 |
刊名 | CHEMPHYSCHEM
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出版日期 | 2008-07-14 |
卷号 | 9期号:10页码:1409-1415 |
关键词 | Electron Transfer Energy Transfer Photochemistry Photosynthesis Porphyrin |
ISSN号 | 1439-4235 |
DOI | 10.1002/cphc.200800028 |
英文摘要 | Two compounds containing a porphyrin dimer and a perylene tetracarboxylic diimide (PDI) linked by phenyl (1) or ethylene groups (2) ore prepared. The photophysical properties of these two compounds ore investigated by steady state electronic absorption and fluorescence spectra and lifetime measurements. The ground state absorption spectra reveal intense interactions between the porphyrin units within the porphyrin dimer, but no interactions between the porphyirn dimer and PDI. The fluorescence spectra suggest efficient energy transfer from PDI to porphyrin accompanied by less efficient electron transfer from porphyrin to PDI. The energy transfer is not affected by the dimeric structure of porphyrin or the linkage between the porphyrin dimer and PDI. However, the electron transfer from porphyrin to PDI is significantly affected by either the linkage between the donor and the acceptor or the polarity of the solvents. The dimeric structure of the porphyrin units in these compounds significantly promotes electron transfer in nonpolar, but not in polar, solvents. |
语种 | 英语 |
WOS记录号 | WOS:000257822200011 |
出版者 | WILEY-V C H VERLAG GMBH |
源URL | [http://ir.iccas.ac.cn/handle/121111/63503] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Li, Xiyou |
作者单位 | 1.Shandong Univ, Dept Chem, Jinan 250100, Peoples R China 2.Chinese Acad Sci, Key Lab Photochem CAS, Inst Chem, Beijing 100800, Peoples R China 3.Chinese Acad Sci, Inst Phys, Beijing 100800, Peoples R China |
推荐引用方式 GB/T 7714 | Xu, Wei,Chen, Hailong,Wang, Yanfeng,et al. Photoinduced electron and energy transfer in dyads of porphyrin dimer and perylene tetracarboxylic diimide[J]. CHEMPHYSCHEM,2008,9(10):1409-1415. |
APA | Xu, Wei.,Chen, Hailong.,Wang, Yanfeng.,Zhao, Chuntao.,Li, Xiyou.,...&Weng, Yuxiang.(2008).Photoinduced electron and energy transfer in dyads of porphyrin dimer and perylene tetracarboxylic diimide.CHEMPHYSCHEM,9(10),1409-1415. |
MLA | Xu, Wei,et al."Photoinduced electron and energy transfer in dyads of porphyrin dimer and perylene tetracarboxylic diimide".CHEMPHYSCHEM 9.10(2008):1409-1415. |
入库方式: OAI收割
来源:化学研究所
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