中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis of bimetallic systems using replacement reactions

文献类型:期刊论文

作者Wang, Songrui1; He, Jian'an1; Xie, Jinglin1; Zhu, Yuexiang1; Xie, Youchang1; Chen, Jingguang G.2
刊名APPLIED SURFACE SCIENCE
出版日期2008-01-30
卷号254期号:7页码:2102-2109
关键词Bimetallic Catalysts Monolayer Dispersion Surface Solid Solution
ISSN号0169-4332
DOI10.1016/j.apsusc.2007.08.063
英文摘要Series of bimetallic systems were prepared by replacement reactions and characterized by XRD and XPS. The results suggest that the ad-metals are monolayer dispersed on the surface of sub-metal in Pd(Pt, Cu)/Co(Ni) systems, while in Pd(Pt, Au)/Cu systems surface solid solution is formed. In Ag(Au)/Co(Ni) and Ag/Cu systems no interaction between the metals is observed just as in the simple mixture of the respective crystallites. The outermost electronic configurations, the atomic radius of the metals, and the low-preparation temperature seem to be important factors for the different states of these bimetallic catalysts. (C) 2007 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000253176600040
出版者ELSEVIER SCIENCE BV
源URL[http://ir.iccas.ac.cn/handle/121111/63555]  
专题中国科学院化学研究所
通讯作者Zhu, Yuexiang
作者单位1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Struct Chem Unstable & Stable Speci, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China
2.Univ Delaware, Ctr Catalyt Sci & Technol, Dept Chem Engn, Newark, DE 19716 USA
推荐引用方式
GB/T 7714
Wang, Songrui,He, Jian'an,Xie, Jinglin,et al. Synthesis of bimetallic systems using replacement reactions[J]. APPLIED SURFACE SCIENCE,2008,254(7):2102-2109.
APA Wang, Songrui,He, Jian'an,Xie, Jinglin,Zhu, Yuexiang,Xie, Youchang,&Chen, Jingguang G..(2008).Synthesis of bimetallic systems using replacement reactions.APPLIED SURFACE SCIENCE,254(7),2102-2109.
MLA Wang, Songrui,et al."Synthesis of bimetallic systems using replacement reactions".APPLIED SURFACE SCIENCE 254.7(2008):2102-2109.

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来源:化学研究所

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