The further understanding of chain topology effect on the properties of single polymer in good solvent: Special behaviors of single tadpole chain
文献类型：期刊论文
| 作者 | Fu, Cui-Liu1; Sun, Zhao-Yan1; Li, Hong-Fei1; An, Li-Jia1; Tong, Zhen2 |
| 刊名 | POLYMER
 |
| 出版日期 | 2008-08-11 |
| 卷号 | 49期号:17页码:3832-3837 |
| 关键词 | Tadpole Polymer Molecular Dynamic Simulation Zimm Model |
| ISSN号 | 0032-3861 |
| DOI | 10.1016/j.polymer.2008.06.045 |
| 英文摘要 | Chain topology strongly affects the static and dynamic properties of polymer melts and polymers in dilute solution. For different chain architectures, such as ring and linear polymers, the molecular size and the diffusion behavior are different. To further understand the chain topology effect on the static and dynamic properties of polymers, we focus on the tadpole polymer which consists of a cyclic chain attached with one or more linear tails. It is found that both the number and the length of linear tails play important roles on the properties of the tadpole polymers in dilute solution. For the tadpole polymers with fixed linear tail length and number, with increasing the degree of polymerization of tadpole polymers, a transition from linear-like to ring-like behavior is observed for both the static and dynamic properties. By studying the radii of gyration for different chains, we define a ratio of the number of monomers in linear tails (N(tail)) to the total degree of polymerization (N). and found that when the ratio N(tail)/N is more than about 0.73, tadpole chains behave as linear chains, while, when N(tail)/N is less than about 0.29, they behave as ring chains. This result will be helpful in further understanding of the chain topology dependence on the static and dynamic properties of polymer in dilute solution. Furthermore, the tadpole polymers behave as what Zimm theory expected before they deviate from the linear-like regime, or after they reach the ring-like regime, however, in the intermediate regime, the behavior of tadpole polymer does not show what Zimm model expected. (C) 2008 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000258616200029 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/63643]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Zhao-Yan |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.S China Univ Technol, Res Inst Mat Sci, Guangzhou 510641, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fu, Cui-Liu,Sun, Zhao-Yan,Li, Hong-Fei,et al. The further understanding of chain topology effect on the properties of single polymer in good solvent: Special behaviors of single tadpole chain[J]. POLYMER,2008,49(17):3832-3837. |
| APA | Fu, Cui-Liu,Sun, Zhao-Yan,Li, Hong-Fei,An, Li-Jia,&Tong, Zhen.(2008).The further understanding of chain topology effect on the properties of single polymer in good solvent: Special behaviors of single tadpole chain.POLYMER,49(17),3832-3837. |
| MLA | Fu, Cui-Liu,et al."The further understanding of chain topology effect on the properties of single polymer in good solvent: Special behaviors of single tadpole chain".POLYMER 49.17(2008):3832-3837. |
入库方式： OAI收割
来源：化学研究所
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