Succinoylation of sugarcane bagasse under ultrasound irradiation
文献类型:期刊论文
作者 | Liu, C. F.1; Sun, R. C.1,2; Qin, M. H.3; Zhang, A. P.1,4; Ren, J. L.1; Ye, J.1; Luo, W.5; Cao, Z. N.5 |
刊名 | BIORESOURCE TECHNOLOGY
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出版日期 | 2008-03-01 |
卷号 | 99期号:5页码:1465-1473 |
关键词 | Sugarcane Bagasse Succinic Anhydride Chemical Modification Succinoylation Ultrasound Irradiation |
ISSN号 | 0960-8524 |
DOI | 10.1016/j.biortech.2007.01.062 |
英文摘要 | The chemical modification of sugarcane bagasse with succinic anhydride using pyridine as solvent after ultrasound irradiation was studied. The optimized parameters included ultrasound irradiating time 0-50 min, reaction time 30-120 min, succinic anhydride concentration by the ratio of dried sugarcane bagasse to succinic anhydride from 1:0.25 to 1:1.50, and reaction temperature 75-115 degrees C are required in the process. The extent of succinoylation was measured by the weight percent gain (WPG), which increased with increments of reaction time, succinic anhydride concentration, and reaction temperature. The ultrasound irradiation has a positive effect on bagasse succinoylation process. On the other hand, the ultrasonic pre-treatment application broke down the cell wall polymers, resulting in, therefore, a negative effect on the WPG. Evidences of succinoylation were also provided by FT-IR and CP MAS C-13 NMR and the results showed that the succinoylation at C-2 and C-3 occurred. The thermal stability of the succinylated bagasse decreased upon chemical modification. (C) 2007 Elsevier Ltd. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000253250900072 |
出版者 | ELSEVIER SCI LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/63667] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Sun, R. C. |
作者单位 | 1.S China Univ Technol, State Key Lab Pulp & Paper Engn, Guangzhou, Peoples R China 2.Beijing Forestry Univ, Coll Mat Sci & Technol, Beijing, Peoples R China 3.Shandong Inst Light Ind, Shandong Key Lab Pulp & Paper Engn, Jinan, Peoples R China 4.Chinese Acad Sci, Inst Chem, Key Lab Cellulos & Lignocellulos Chem, Guangzhou, Peoples R China 5.S China Univ Technol, Ctr Instrument & Anal, Guangzhou, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, C. F.,Sun, R. C.,Qin, M. H.,et al. Succinoylation of sugarcane bagasse under ultrasound irradiation[J]. BIORESOURCE TECHNOLOGY,2008,99(5):1465-1473. |
APA | Liu, C. F..,Sun, R. C..,Qin, M. H..,Zhang, A. P..,Ren, J. L..,...&Cao, Z. N..(2008).Succinoylation of sugarcane bagasse under ultrasound irradiation.BIORESOURCE TECHNOLOGY,99(5),1465-1473. |
MLA | Liu, C. F.,et al."Succinoylation of sugarcane bagasse under ultrasound irradiation".BIORESOURCE TECHNOLOGY 99.5(2008):1465-1473. |
入库方式: OAI收割
来源:化学研究所
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