Formation mechanism of polyaniline nanotubes by a simplified template-free method
文献类型：期刊论文
| 作者 | Ding, Hangjun1,2; Shen, Jiaoyan3; Wan, Meixiang1; Chen, Zhaojia3 |
| 刊名 | MACROMOLECULAR CHEMISTRY AND PHYSICS
 |
| 出版日期 | 2008-04-22 |
| 卷号 | 209期号:8页码:864-871 |
| 关键词 | Conducting Polymers Micelles Nanotechnology Polyaniline Self-assembly Templates |
| ISSN号 | 1022-1352 |
| DOI | 10.1002/macp.200700624 |
| 英文摘要 | PANI nanotubes with diameters of 100-150 nm with conductivities of single nanotubes as high as 30.6 S . cm(-1) were directly oxidized with APS in the absence of hard templates and acidic dopants. The high conductivity was shown to result from protons produced during the polymerization. The pH decreases with increasing polymerization time, and the morphology changes from hollow spheres to short and long tubes. It is proposed that the micelles formed by the aniline monomer in aqueous solution serve as a soft template for forming hollow spheres at the initial stage. As the polymerization proceeds, these hollow spheres are linearly aggregated and elongated to form short and long tubes. |
| 语种 | 英语 |
| WOS记录号 | WOS:000255716700010 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/63675]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wan, Meixiang |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China 2.Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China 3.Chinese Acad Sci, Inst Phys, Lab Extreme Condit Phys, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ding, Hangjun,Shen, Jiaoyan,Wan, Meixiang,et al. Formation mechanism of polyaniline nanotubes by a simplified template-free method[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS,2008,209(8):864-871. |
| APA | Ding, Hangjun,Shen, Jiaoyan,Wan, Meixiang,&Chen, Zhaojia.(2008).Formation mechanism of polyaniline nanotubes by a simplified template-free method.MACROMOLECULAR CHEMISTRY AND PHYSICS,209(8),864-871. |
| MLA | Ding, Hangjun,et al."Formation mechanism of polyaniline nanotubes by a simplified template-free method".MACROMOLECULAR CHEMISTRY AND PHYSICS 209.8(2008):864-871. |
入库方式： OAI收割
来源：化学研究所
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