Metal Al produced by H-2 plasma reduction of AlCl3: A thermodynamic and kinetic study on the plasma chemistry
文献类型：期刊论文
| 作者 | Zheng, Jie1; Sun, Bo1; Yang, Rong1; Song, Xubo1; Li, Xingguo1,2; Pu, Yikang3 |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY B
 |
| 出版日期 | 2008-10-09 |
| 卷号 | 112期号:40页码:12748-12752 |
| ISSN号 | 1520-6106 |
| DOI | 10.1021/jp8035204 |
| 英文摘要 | In this paper we reported that low temperature plasma may reverse the direction of a chemical reaction. The thermodynamically forbidden reaction between H-2 and AlCl3 was able to take place with the assistance of low temperature plasma, yielding metal Al. The plasma chemistry of the reaction was investigated by optical emission spectroscopy, which suggested that the dissociation of H-2 and AlCl3 molecules by plasma led the reaction to a thermodynamically favorable one by creating reaction channels with low Gibbs free energy change. The addition of Ar promoted the reaction kinetics dramatically, which was attributed to the enhanced dissociation of AlCl3 molecules by excited Ar species. |
| 语种 | 英语 |
| WOS记录号 | WOS:000259780200027 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/63811]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Xingguo |
| 作者单位 | 1.Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, BNLMS, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Peking Univ, Coll Engn, Beijing 100871, Peoples R China 3.Tsinghua Univ, Dept Engn Phys, Beijing 100084, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, Jie,Sun, Bo,Yang, Rong,et al. Metal Al produced by H-2 plasma reduction of AlCl3: A thermodynamic and kinetic study on the plasma chemistry[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2008,112(40):12748-12752. |
| APA | Zheng, Jie,Sun, Bo,Yang, Rong,Song, Xubo,Li, Xingguo,&Pu, Yikang.(2008).Metal Al produced by H-2 plasma reduction of AlCl3: A thermodynamic and kinetic study on the plasma chemistry.JOURNAL OF PHYSICAL CHEMISTRY B,112(40),12748-12752. |
| MLA | Zheng, Jie,et al."Metal Al produced by H-2 plasma reduction of AlCl3: A thermodynamic and kinetic study on the plasma chemistry".JOURNAL OF PHYSICAL CHEMISTRY B 112.40(2008):12748-12752. |
入库方式： OAI收割
来源：化学研究所
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